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Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate

In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted penta­gonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate li...

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Detalles Bibliográficos
Autores principales: Zhang, Shi Guo, Zhang, Hui Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009023/
https://www.ncbi.nlm.nih.gov/pubmed/21588828
http://dx.doi.org/10.1107/S1600536810039735
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author Zhang, Shi Guo
Zhang, Hui Ming
author_facet Zhang, Shi Guo
Zhang, Hui Ming
author_sort Zhang, Shi Guo
collection PubMed
description In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted penta­gonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, inter­molecular O—H⋯O and O—H⋯N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π–π stacking inter­action between symmetry-related benzene rings, with a centroid–centroid distance of 3.598 (3) Å.
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spelling pubmed-30090232010-12-30 Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate Zhang, Shi Guo Zhang, Hui Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted penta­gonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, inter­molecular O—H⋯O and O—H⋯N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π–π stacking inter­action between symmetry-related benzene rings, with a centroid–centroid distance of 3.598 (3) Å. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009023/ /pubmed/21588828 http://dx.doi.org/10.1107/S1600536810039735 Text en © Zhang and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Shi Guo
Zhang, Hui Ming
Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
title Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
title_full Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
title_fullStr Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
title_full_unstemmed Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
title_short Diaqua­(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
title_sort diaqua­(nitrato-κ(2) o,o′)[2-(1h-1,2,4-triazol-1-yl-κn (2))-1,10-phenanthroline-κ(2) n,n′]cadmium(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009023/
https://www.ncbi.nlm.nih.gov/pubmed/21588828
http://dx.doi.org/10.1107/S1600536810039735
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