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Diaqua(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate
In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted pentagonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate li...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009023/ https://www.ncbi.nlm.nih.gov/pubmed/21588828 http://dx.doi.org/10.1107/S1600536810039735 |
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author | Zhang, Shi Guo Zhang, Hui Ming |
author_facet | Zhang, Shi Guo Zhang, Hui Ming |
author_sort | Zhang, Shi Guo |
collection | PubMed |
description | In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted pentagonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, intermolecular O—H⋯O and O—H⋯N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π–π stacking interaction between symmetry-related benzene rings, with a centroid–centroid distance of 3.598 (3) Å. |
format | Text |
id | pubmed-3009023 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090232010-12-30 Diaqua(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate Zhang, Shi Guo Zhang, Hui Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted pentagonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, intermolecular O—H⋯O and O—H⋯N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π–π stacking interaction between symmetry-related benzene rings, with a centroid–centroid distance of 3.598 (3) Å. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009023/ /pubmed/21588828 http://dx.doi.org/10.1107/S1600536810039735 Text en © Zhang and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Shi Guo Zhang, Hui Ming Diaqua(nitrato-κ(2) O,O′)[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) nitrate |
title | Diaqua(nitrato-κ(2)
O,O′)[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) nitrate |
title_full | Diaqua(nitrato-κ(2)
O,O′)[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) nitrate |
title_fullStr | Diaqua(nitrato-κ(2)
O,O′)[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) nitrate |
title_full_unstemmed | Diaqua(nitrato-κ(2)
O,O′)[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) nitrate |
title_short | Diaqua(nitrato-κ(2)
O,O′)[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) nitrate |
title_sort | diaqua(nitrato-κ(2)
o,o′)[2-(1h-1,2,4-triazol-1-yl-κn
(2))-1,10-phenanthroline-κ(2)
n,n′]cadmium(ii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009023/ https://www.ncbi.nlm.nih.gov/pubmed/21588828 http://dx.doi.org/10.1107/S1600536810039735 |
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