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N,N′-Bis(3-methyl­phen­yl)propane­diamide

The mol­ecular structure of the title compound, C(17)H(18)N(2)O(2), is symmetrical around the central C atom. The two halves of the mol­ecule are related by a twofold rotation axis. In each half of the mol­ecule, the structure is stabilized by intra­molecular C—H⋯O hydrogen bonds. Furthermore, each...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Rodrigues, Vinola Z., Kožíšek, Jozef, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009026/
https://www.ncbi.nlm.nih.gov/pubmed/21589191
http://dx.doi.org/10.1107/S1600536810044089
Descripción
Sumario:The mol­ecular structure of the title compound, C(17)H(18)N(2)O(2), is symmetrical around the central C atom. The two halves of the mol­ecule are related by a twofold rotation axis. In each half of the mol­ecule, the structure is stabilized by intra­molecular C—H⋯O hydrogen bonds. Furthermore, each amide group is almost coplanar with the adjacent benzene ring [dihedral angle is 9.2 (2)°]. The planes of the amide groups are inclined at an angle of 68.5 (1)°, while the two benzene rings make a dihedral angle of 70.40 (3)°. In the crystal, mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds into chains running along the c axis. Neighbouring chains are weakly coupled by π–π stacking inter­actions [centroid–centroid distance = 3.7952 (8) Å].