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N,N′-Bis(3-methylphenyl)propanediamide
The molecular structure of the title compound, C(17)H(18)N(2)O(2), is symmetrical around the central C atom. The two halves of the molecule are related by a twofold rotation axis. In each half of the molecule, the structure is stabilized by intramolecular C—H⋯O hydrogen bonds. Furthermore, each...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009026/ https://www.ncbi.nlm.nih.gov/pubmed/21589191 http://dx.doi.org/10.1107/S1600536810044089 |
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author | Gowda, B. Thimme Tokarčík, Miroslav Rodrigues, Vinola Z. Kožíšek, Jozef Fuess, Hartmut |
author_facet | Gowda, B. Thimme Tokarčík, Miroslav Rodrigues, Vinola Z. Kožíšek, Jozef Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | The molecular structure of the title compound, C(17)H(18)N(2)O(2), is symmetrical around the central C atom. The two halves of the molecule are related by a twofold rotation axis. In each half of the molecule, the structure is stabilized by intramolecular C—H⋯O hydrogen bonds. Furthermore, each amide group is almost coplanar with the adjacent benzene ring [dihedral angle is 9.2 (2)°]. The planes of the amide groups are inclined at an angle of 68.5 (1)°, while the two benzene rings make a dihedral angle of 70.40 (3)°. In the crystal, molecules are linked by intermolecular N—H⋯O hydrogen bonds into chains running along the c axis. Neighbouring chains are weakly coupled by π–π stacking interactions [centroid–centroid distance = 3.7952 (8) Å]. |
format | Text |
id | pubmed-3009026 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090262010-12-30 N,N′-Bis(3-methylphenyl)propanediamide Gowda, B. Thimme Tokarčík, Miroslav Rodrigues, Vinola Z. Kožíšek, Jozef Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecular structure of the title compound, C(17)H(18)N(2)O(2), is symmetrical around the central C atom. The two halves of the molecule are related by a twofold rotation axis. In each half of the molecule, the structure is stabilized by intramolecular C—H⋯O hydrogen bonds. Furthermore, each amide group is almost coplanar with the adjacent benzene ring [dihedral angle is 9.2 (2)°]. The planes of the amide groups are inclined at an angle of 68.5 (1)°, while the two benzene rings make a dihedral angle of 70.40 (3)°. In the crystal, molecules are linked by intermolecular N—H⋯O hydrogen bonds into chains running along the c axis. Neighbouring chains are weakly coupled by π–π stacking interactions [centroid–centroid distance = 3.7952 (8) Å]. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009026/ /pubmed/21589191 http://dx.doi.org/10.1107/S1600536810044089 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Tokarčík, Miroslav Rodrigues, Vinola Z. Kožíšek, Jozef Fuess, Hartmut N,N′-Bis(3-methylphenyl)propanediamide |
title |
N,N′-Bis(3-methylphenyl)propanediamide |
title_full |
N,N′-Bis(3-methylphenyl)propanediamide |
title_fullStr |
N,N′-Bis(3-methylphenyl)propanediamide |
title_full_unstemmed |
N,N′-Bis(3-methylphenyl)propanediamide |
title_short |
N,N′-Bis(3-methylphenyl)propanediamide |
title_sort | n,n′-bis(3-methylphenyl)propanediamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009026/ https://www.ncbi.nlm.nih.gov/pubmed/21589191 http://dx.doi.org/10.1107/S1600536810044089 |
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