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catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2) O (1):O (4);κ(2) O (4):O (1)] tetrahydrate], a polymeric chain structure
In the title complex, {[Cd(C(9)H(8)NO(4))(2)(H(2)O)(2)]·4H(2)O}(n), the Cd(II) atom (site symmetry 2) is coordinated by six O atoms from four crystallographically related 1-(1,2-dicarboxylate)pyridin-1-ium ligands (L) and from two water molecules in a distorted octahedral geometry. Paired L ligands...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009031/ https://www.ncbi.nlm.nih.gov/pubmed/21588879 http://dx.doi.org/10.1107/S1600536810041607 |
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author | Liu, Zhi-Hua Zhu, Sen |
author_facet | Liu, Zhi-Hua Zhu, Sen |
author_sort | Liu, Zhi-Hua |
collection | PubMed |
description | In the title complex, {[Cd(C(9)H(8)NO(4))(2)(H(2)O)(2)]·4H(2)O}(n), the Cd(II) atom (site symmetry 2) is coordinated by six O atoms from four crystallographically related 1-(1,2-dicarboxylate)pyridin-1-ium ligands (L) and from two water molecules in a distorted octahedral geometry. Paired L ligands connect Cd(II) atoms into a chain motif parallel to [001], which is further interlinked by O—H⋯O hydrogen bonds into a three-dimensional supramolecular net. |
format | Text |
id | pubmed-3009031 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090312010-12-30 catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2) O (1):O (4);κ(2) O (4):O (1)] tetrahydrate], a polymeric chain structure Liu, Zhi-Hua Zhu, Sen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cd(C(9)H(8)NO(4))(2)(H(2)O)(2)]·4H(2)O}(n), the Cd(II) atom (site symmetry 2) is coordinated by six O atoms from four crystallographically related 1-(1,2-dicarboxylate)pyridin-1-ium ligands (L) and from two water molecules in a distorted octahedral geometry. Paired L ligands connect Cd(II) atoms into a chain motif parallel to [001], which is further interlinked by O—H⋯O hydrogen bonds into a three-dimensional supramolecular net. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009031/ /pubmed/21588879 http://dx.doi.org/10.1107/S1600536810041607 Text en © Liu and Zhu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Zhi-Hua Zhu, Sen catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2) O (1):O (4);κ(2) O (4):O (1)] tetrahydrate], a polymeric chain structure |
title |
catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2)
O
(1):O
(4);κ(2)
O
(4):O
(1)] tetrahydrate], a polymeric chain structure |
title_full |
catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2)
O
(1):O
(4);κ(2)
O
(4):O
(1)] tetrahydrate], a polymeric chain structure |
title_fullStr |
catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2)
O
(1):O
(4);κ(2)
O
(4):O
(1)] tetrahydrate], a polymeric chain structure |
title_full_unstemmed |
catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2)
O
(1):O
(4);κ(2)
O
(4):O
(1)] tetrahydrate], a polymeric chain structure |
title_short |
catena-Poly[[[diaquacadmium(II)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2)
O
(1):O
(4);κ(2)
O
(4):O
(1)] tetrahydrate], a polymeric chain structure |
title_sort | catena-poly[[[diaquacadmium(ii)]bis[μ-2-(pyridinium-1-yl)butanedioato]-κ(2)
o
(1):o
(4);κ(2)
o
(4):o
(1)] tetrahydrate], a polymeric chain structure |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009031/ https://www.ncbi.nlm.nih.gov/pubmed/21588879 http://dx.doi.org/10.1107/S1600536810041607 |
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