3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide

In the title compound, C(14)H(15)N(3)O(2), the phenyl­ene ring is disordered over two orientations. As a result, the almost planar pyrazole ring (r.m.s. deviation = 0.004 Å) forms dihedral angles of 59.8 (1) and −61.9 (1)° with the two orientations of the phenyl­ene ring. The dihedral angle between...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Bari, Ahmed, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009041/
https://www.ncbi.nlm.nih.gov/pubmed/21589170
http://dx.doi.org/10.1107/S1600536810043928
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author Abdel-Aziz, Hatem A.
Bari, Ahmed
Ng, Seik Weng
author_facet Abdel-Aziz, Hatem A.
Bari, Ahmed
Ng, Seik Weng
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description In the title compound, C(14)H(15)N(3)O(2), the phenyl­ene ring is disordered over two orientations. As a result, the almost planar pyrazole ring (r.m.s. deviation = 0.004 Å) forms dihedral angles of 59.8 (1) and −61.9 (1)° with the two orientations of the phenyl­ene ring. The dihedral angle between the two orientations is 59.2 (1)°. In the crystal, inversion dimers lined by pairs of N—H⋯O hydrogen bonds occur; there is also an intramolecular N—H⋯O bond.
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spelling pubmed-30090412010-12-30 3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide Abdel-Aziz, Hatem A. Bari, Ahmed Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(15)N(3)O(2), the phenyl­ene ring is disordered over two orientations. As a result, the almost planar pyrazole ring (r.m.s. deviation = 0.004 Å) forms dihedral angles of 59.8 (1) and −61.9 (1)° with the two orientations of the phenyl­ene ring. The dihedral angle between the two orientations is 59.2 (1)°. In the crystal, inversion dimers lined by pairs of N—H⋯O hydrogen bonds occur; there is also an intramolecular N—H⋯O bond. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009041/ /pubmed/21589170 http://dx.doi.org/10.1107/S1600536810043928 Text en © Abdel-Aziz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Bari, Ahmed
Ng, Seik Weng
3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide
title 3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide
title_full 3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide
title_fullStr 3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide
title_full_unstemmed 3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide
title_short 3-Acetyl-5-methyl-1-(4-methyl­phen­yl)-1H-pyrazole-4-carboxamide
title_sort 3-acetyl-5-methyl-1-(4-methyl­phen­yl)-1h-pyrazole-4-carboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009041/
https://www.ncbi.nlm.nih.gov/pubmed/21589170
http://dx.doi.org/10.1107/S1600536810043928
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AT bariahmed 3acetyl5methyl14methylphenyl1hpyrazole4carboxamide
AT ngseikweng 3acetyl5methyl14methylphenyl1hpyrazole4carboxamide

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