Cargando…

catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]

The hydro­thermal reaction of cadmium(II) nitrate with 5-amino-2,4,6-triiodo­isophthalic acid and pyridine in DMF solution leads to the formation of the title compound, [Cd(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra­hedral geometry,...

Descripción completa

Detalles Bibliográficos
Autor principal: Zou, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009045/
https://www.ncbi.nlm.nih.gov/pubmed/21588812
http://dx.doi.org/10.1107/S1600536810039498
_version_ 1782194592396869632
author Zou, Yang
author_facet Zou, Yang
author_sort Zou, Yang
collection PubMed
description The hydro­thermal reaction of cadmium(II) nitrate with 5-amino-2,4,6-triiodo­isophthalic acid and pyridine in DMF solution leads to the formation of the title compound, [Cd(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra­hedral geometry, which lies on a crystallographic twofold rotation axis. The Cd(2+ )ion is bonded to two N atoms from two pyridine ligands and two carboxyl­ate O atoms from two 5-amino-2,4,6-triiodo­isophthalate anions. The Cd—O distances are 2.429 (5) and 2.305 (5) Å and the Cd—N distance is 2.236 (8) Å. The two carboxyl­ate groups of individual 5-amino-2,4,6-triiodo­isophthalate anions act as a bridge to the Cd(2+) atoms. leading to a chain structure along the c axis.
format Text
id pubmed-3009045
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090452010-12-30 catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato] Zou, Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The hydro­thermal reaction of cadmium(II) nitrate with 5-amino-2,4,6-triiodo­isophthalic acid and pyridine in DMF solution leads to the formation of the title compound, [Cd(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra­hedral geometry, which lies on a crystallographic twofold rotation axis. The Cd(2+ )ion is bonded to two N atoms from two pyridine ligands and two carboxyl­ate O atoms from two 5-amino-2,4,6-triiodo­isophthalate anions. The Cd—O distances are 2.429 (5) and 2.305 (5) Å and the Cd—N distance is 2.236 (8) Å. The two carboxyl­ate groups of individual 5-amino-2,4,6-triiodo­isophthalate anions act as a bridge to the Cd(2+) atoms. leading to a chain structure along the c axis. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009045/ /pubmed/21588812 http://dx.doi.org/10.1107/S1600536810039498 Text en © Yang Zou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zou, Yang
catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_full catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_fullStr catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_full_unstemmed catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_short catena-Poly[[dipyridine­cadmium(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_sort catena-poly[[dipyridine­cadmium(ii)]-μ-5-amino-2,4,6-triiodo­isophthalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009045/
https://www.ncbi.nlm.nih.gov/pubmed/21588812
http://dx.doi.org/10.1107/S1600536810039498
work_keys_str_mv AT zouyang catenapolydipyridinecadmiumiim5amino246triiodoisophthalato