Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate

In the crystal structure of the title compound, C(15)H(16)N(2)O(5)S, the azomethine adopts the E configuration. The two heterocyclic rings adopt an anti­periplanar orientation. The mean planes of the thio­phene and furan rings are twisted by 2.51 (4)°. The crystal structure exhibits inter­molecular...

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Detalles Bibliográficos
Autores principales: Dufresne, Stéphane, Skene, W. G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009046/
https://www.ncbi.nlm.nih.gov/pubmed/21589183
http://dx.doi.org/10.1107/S1600536810043746
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author Dufresne, Stéphane
Skene, W. G.
author_facet Dufresne, Stéphane
Skene, W. G.
author_sort Dufresne, Stéphane
collection PubMed
description In the crystal structure of the title compound, C(15)H(16)N(2)O(5)S, the azomethine adopts the E configuration. The two heterocyclic rings adopt an anti­periplanar orientation. The mean planes of the thio­phene and furan rings are twisted by 2.51 (4)°. The crystal structure exhibits inter­molecular N—H⋯O hydrogen bonding. π–π stacking is also observed, the centroid-to-centroid distance being 3.770 (4) Å.
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spelling pubmed-30090462010-12-30 Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate Dufresne, Stéphane Skene, W. G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(15)H(16)N(2)O(5)S, the azomethine adopts the E configuration. The two heterocyclic rings adopt an anti­periplanar orientation. The mean planes of the thio­phene and furan rings are twisted by 2.51 (4)°. The crystal structure exhibits inter­molecular N—H⋯O hydrogen bonding. π–π stacking is also observed, the centroid-to-centroid distance being 3.770 (4) Å. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009046/ /pubmed/21589183 http://dx.doi.org/10.1107/S1600536810043746 Text en © Dufresne and Skene 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dufresne, Stéphane
Skene, W. G.
Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
title Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
title_full Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
title_fullStr Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
title_full_unstemmed Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
title_short Diethyl 2-amino-5-[(E)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
title_sort diethyl 2-amino-5-[(e)-(furan-2-yl­methyl­idene)amino]­thio­phene-3,4-di­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009046/
https://www.ncbi.nlm.nih.gov/pubmed/21589183
http://dx.doi.org/10.1107/S1600536810043746
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