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2-[(E)-4-(Dimethylamino)styryl]-1-methylpyridinium 4-chlorobenzenesulfonate monohydrate
In the title hydrated molecular salt, C(16)H(19)N(2) (+)·C(6)H(4)ClO(3)S(−)·H(2)O, the 2-[4-(dimethylamino)styryl]-1-methylpyridinium cation exists in an E configuration with respect to the C=C bond and is slightly twisted, with the dihedral angle between the pyridinium and benzene rings being...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009047/ https://www.ncbi.nlm.nih.gov/pubmed/21589156 http://dx.doi.org/10.1107/S1600536810043230 |
Sumario: | In the title hydrated molecular salt, C(16)H(19)N(2) (+)·C(6)H(4)ClO(3)S(−)·H(2)O, the 2-[4-(dimethylamino)styryl]-1-methylpyridinium cation exists in an E configuration with respect to the C=C bond and is slightly twisted, with the dihedral angle between the pyridinium and benzene rings being 9.33 (10)°. In the crystal structure, the packing is stabilized by O—H⋯O hydrogen bonds and weak C—H⋯O interactions, which link the cations, anions and water molecules into chains propagating in [010]. These chains are stacked along the a axis by π–π interactions, with centroid-to-centroid distances of 3.6429 (12) and 3.6879 (12) Å; weak C—H⋯π interactions are also observed. |
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