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2-[(E)-4-(Dimethyl­amino)­styr­yl]-1-methyl­pyridinium 4-chloro­benzene­sulfonate monohydrate

In the title hydrated mol­ecular salt, C(16)H(19)N(2) (+)·C(6)H(4)ClO(3)S(−)·H(2)O, the 2-[4-(dimethyl­amino)­styr­yl]-1-methyl­pyridinium cation exists in an E configuration with respect to the C=C bond and is slightly twisted, with the dihedral angle between the pyridinium and benzene rings being...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chanawanno, Kullapa, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009047/
https://www.ncbi.nlm.nih.gov/pubmed/21589156
http://dx.doi.org/10.1107/S1600536810043230
Descripción
Sumario:In the title hydrated mol­ecular salt, C(16)H(19)N(2) (+)·C(6)H(4)ClO(3)S(−)·H(2)O, the 2-[4-(dimethyl­amino)­styr­yl]-1-methyl­pyridinium cation exists in an E configuration with respect to the C=C bond and is slightly twisted, with the dihedral angle between the pyridinium and benzene rings being 9.33 (10)°. In the crystal structure, the packing is stabilized by O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions, which link the cations, anions and water mol­ecules into chains propagating in [010]. These chains are stacked along the a axis by π–π inter­actions, with centroid-to-centroid distances of 3.6429 (12) and 3.6879 (12) Å; weak C—H⋯π inter­actions are also observed.