cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)

In the title complex, cis-[PtCl(2)(C(11)H(9)N)(2)], the Pt(II) ion is situated in a slightly distorted square-planar environment coordinated by two N atoms from two 2-phenyl­pyridine ligands and two Cl atoms. The two pyridyl planes are inclined with dihedral angles of 59.1 (2) and 61.84 (19)° with r...

Descripción completa

Detalles Bibliográficos
Autores principales: Yoshinari, Nobuto, Kitani, Naoki, Konno, Takumi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009048/
https://www.ncbi.nlm.nih.gov/pubmed/21588912
http://dx.doi.org/10.1107/S160053681004393X
Descripción
Sumario:In the title complex, cis-[PtCl(2)(C(11)H(9)N)(2)], the Pt(II) ion is situated in a slightly distorted square-planar environment coordinated by two N atoms from two 2-phenyl­pyridine ligands and two Cl atoms. The two pyridyl planes are inclined with dihedral angles of 59.1 (2) and 61.84 (19)° with respect to the PtCl(2)N(2) plane. In the crystal, the complex mol­ecules display inter- and intra­molecular π–π stacking inter­actions, with centroid-centroid distances of 3.806 (5)–3.845 (5) Å, which form a one-dimensional column structure along the a axis.

Ejemplares similares