cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)

In the title complex, cis-[PtCl(2)(C(11)H(9)N)(2)], the Pt(II) ion is situated in a slightly distorted square-planar environment coordinated by two N atoms from two 2-phenyl­pyridine ligands and two Cl atoms. The two pyridyl planes are inclined with dihedral angles of 59.1 (2) and 61.84 (19)° with r...

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Detalles Bibliográficos
Autores principales: Yoshinari, Nobuto, Kitani, Naoki, Konno, Takumi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009048/
https://www.ncbi.nlm.nih.gov/pubmed/21588912
http://dx.doi.org/10.1107/S160053681004393X
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author Yoshinari, Nobuto
Kitani, Naoki
Konno, Takumi
author_facet Yoshinari, Nobuto
Kitani, Naoki
Konno, Takumi
author_sort Yoshinari, Nobuto
collection PubMed
description In the title complex, cis-[PtCl(2)(C(11)H(9)N)(2)], the Pt(II) ion is situated in a slightly distorted square-planar environment coordinated by two N atoms from two 2-phenyl­pyridine ligands and two Cl atoms. The two pyridyl planes are inclined with dihedral angles of 59.1 (2) and 61.84 (19)° with respect to the PtCl(2)N(2) plane. In the crystal, the complex mol­ecules display inter- and intra­molecular π–π stacking inter­actions, with centroid-centroid distances of 3.806 (5)–3.845 (5) Å, which form a one-dimensional column structure along the a axis.
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spelling pubmed-30090482010-12-30 cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II) Yoshinari, Nobuto Kitani, Naoki Konno, Takumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, cis-[PtCl(2)(C(11)H(9)N)(2)], the Pt(II) ion is situated in a slightly distorted square-planar environment coordinated by two N atoms from two 2-phenyl­pyridine ligands and two Cl atoms. The two pyridyl planes are inclined with dihedral angles of 59.1 (2) and 61.84 (19)° with respect to the PtCl(2)N(2) plane. In the crystal, the complex mol­ecules display inter- and intra­molecular π–π stacking inter­actions, with centroid-centroid distances of 3.806 (5)–3.845 (5) Å, which form a one-dimensional column structure along the a axis. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009048/ /pubmed/21588912 http://dx.doi.org/10.1107/S160053681004393X Text en © Yoshinari et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yoshinari, Nobuto
Kitani, Naoki
Konno, Takumi
cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)
title cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)
title_full cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)
title_fullStr cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)
title_full_unstemmed cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)
title_short cis-Dichloridobis(2-phenyl­pyridine-κN)platinum(II)
title_sort cis-dichloridobis(2-phenyl­pyridine-κn)platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009048/
https://www.ncbi.nlm.nih.gov/pubmed/21588912
http://dx.doi.org/10.1107/S160053681004393X
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AT kitaninaoki cisdichloridobis2phenylpyridineknplatinumii
AT konnotakumi cisdichloridobis2phenylpyridineknplatinumii

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