(μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]

The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C—C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl­dithio­carbam...

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Detalles Bibliográficos
Autores principales: Zha, Mei-Qin, Li, Xing, Bing, Yue, Lu, Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009053/
https://www.ncbi.nlm.nih.gov/pubmed/21588882
http://dx.doi.org/10.1107/S1600536810042650
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author Zha, Mei-Qin
Li, Xing
Bing, Yue
Lu, Yue
author_facet Zha, Mei-Qin
Li, Xing
Bing, Yue
Lu, Yue
author_sort Zha, Mei-Qin
collection PubMed
description The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C—C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl­dithio­carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry. Weak inter­molecular C—H⋯S hydrogen bonding is present in the crystal structure.
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spelling pubmed-30090532010-12-30 (μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)] Zha, Mei-Qin Li, Xing Bing, Yue Lu, Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C—C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl­dithio­carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry. Weak inter­molecular C—H⋯S hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009053/ /pubmed/21588882 http://dx.doi.org/10.1107/S1600536810042650 Text en © Zha et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zha, Mei-Qin
Li, Xing
Bing, Yue
Lu, Yue
(μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title (μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full (μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_fullStr (μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full_unstemmed (μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_short (μ-4,4′-Bipyridine-κ(2) N:N′)bis­[bis­(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_sort (μ-4,4′-bipyridine-κ(2) n:n′)bis­[bis­(n,n-dimethyl­dithio­carbamato-κ(2) s,s′)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009053/
https://www.ncbi.nlm.nih.gov/pubmed/21588882
http://dx.doi.org/10.1107/S1600536810042650
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