Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)

The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol­ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = [Image: see text] in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(...

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Detalles Bibliográficos
Autores principales: Xue, Ling-Wei, Zhao, Gan-Qing, Han, Yong-Jun, Chen, Li-Hua, Peng, Qin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009057/
https://www.ncbi.nlm.nih.gov/pubmed/21588797
http://dx.doi.org/10.1107/S1600536810038298
Descripción
Sumario:The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol­ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = [Image: see text] in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(4) geometries arising from two N,O-bidentate Schiff base ligands and two N-bonded thio­cyanate ions. The mol­ecular conformations are reinforced by two intra­molecular N—H⋯O hydrogen bonds.

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