Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)

The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol­ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = [Image: see text] in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(...

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Detalles Bibliográficos
Autores principales: Xue, Ling-Wei, Zhao, Gan-Qing, Han, Yong-Jun, Chen, Li-Hua, Peng, Qin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009057/
https://www.ncbi.nlm.nih.gov/pubmed/21588797
http://dx.doi.org/10.1107/S1600536810038298
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author Xue, Ling-Wei
Zhao, Gan-Qing
Han, Yong-Jun
Chen, Li-Hua
Peng, Qin-Long
author_facet Xue, Ling-Wei
Zhao, Gan-Qing
Han, Yong-Jun
Chen, Li-Hua
Peng, Qin-Long
author_sort Xue, Ling-Wei
collection PubMed
description The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol­ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = [Image: see text] in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(4) geometries arising from two N,O-bidentate Schiff base ligands and two N-bonded thio­cyanate ions. The mol­ecular conformations are reinforced by two intra­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-30090572010-12-30 Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II) Xue, Ling-Wei Zhao, Gan-Qing Han, Yong-Jun Chen, Li-Hua Peng, Qin-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol­ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = [Image: see text] in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(4) geometries arising from two N,O-bidentate Schiff base ligands and two N-bonded thio­cyanate ions. The mol­ecular conformations are reinforced by two intra­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009057/ /pubmed/21588797 http://dx.doi.org/10.1107/S1600536810038298 Text en © Xue et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xue, Ling-Wei
Zhao, Gan-Qing
Han, Yong-Jun
Chen, Li-Hua
Peng, Qin-Long
Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)
title Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)
title_full Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)
title_fullStr Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)
title_full_unstemmed Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)
title_short Bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κN]-6-meth­oxy­phenolato-κO (1)}bis­(thio­cyanato-κN)nickel(II)
title_sort bis{2-[3-(dimethyl­ammonio)­propyl­imino­methyl-κn]-6-meth­oxy­phenolato-κo (1)}bis­(thio­cyanato-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009057/
https://www.ncbi.nlm.nih.gov/pubmed/21588797
http://dx.doi.org/10.1107/S1600536810038298
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