Cargando…

3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one

Each of the cyclohexenone rings in the title compound, C(23)H(27)NO(6), adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the mol­ecule as the respective >C(CH(3)...

Descripción completa

Detalles Bibliográficos
Autores principales: Palakshi Reddy, B., Vijayakumar, V., Sarveswari, S., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009059/
https://www.ncbi.nlm.nih.gov/pubmed/21589000
http://dx.doi.org/10.1107/S1600536810040079
_version_ 1782194595914842112
author Palakshi Reddy, B.
Vijayakumar, V.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Palakshi Reddy, B.
Vijayakumar, V.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Palakshi Reddy, B.
collection PubMed
description Each of the cyclohexenone rings in the title compound, C(23)H(27)NO(6), adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the mol­ecule as the respective >C(CH(3))(2) atoms. The hy­droxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intra­molecular O—H⋯O hydrogen bonds. In the crystal, the presence of C—H⋯O contacts leads to the formation of supra­molecular chains along the b axis. These aggregate into layers that stack along c.
format Text
id pubmed-3009059
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090592010-12-30 3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one Palakshi Reddy, B. Vijayakumar, V. Sarveswari, S. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers Each of the cyclohexenone rings in the title compound, C(23)H(27)NO(6), adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the mol­ecule as the respective >C(CH(3))(2) atoms. The hy­droxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intra­molecular O—H⋯O hydrogen bonds. In the crystal, the presence of C—H⋯O contacts leads to the formation of supra­molecular chains along the b axis. These aggregate into layers that stack along c. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009059/ /pubmed/21589000 http://dx.doi.org/10.1107/S1600536810040079 Text en © Palakshi Reddy et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Palakshi Reddy, B.
Vijayakumar, V.
Sarveswari, S.
Ng, Seik Weng
Tiekink, Edward R. T.
3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title 3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_full 3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_fullStr 3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_full_unstemmed 3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_short 3-Hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_sort 3-hy­droxy-2-[(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)(3-nitro­phen­yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009059/
https://www.ncbi.nlm.nih.gov/pubmed/21589000
http://dx.doi.org/10.1107/S1600536810040079
work_keys_str_mv AT palakshireddyb 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one
AT vijayakumarv 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one
AT sarveswaris 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one
AT ngseikweng 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one
AT tiekinkedwardrt 3hydroxy22hydroxy44dimethyl6oxocyclohex1en1yl3nitrophenylmethyl55dimethylcyclohex2en1one