11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one

In the title compound, C(35)H(28)Br(2)N(2)O(2), the piperidone ring adopts a chair conformation and the five-membered ring of the pyrrolidine ring adopts an envelope conformation. The naphthalene ring system makes dihedral angles of 37.12 (8) and 50.62 (9)° with the terminal bromo-substituted benzen...

Descripción completa

Detalles Bibliográficos
Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Ali, Mohamed Ashraf, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009063/
https://www.ncbi.nlm.nih.gov/pubmed/21589100
http://dx.doi.org/10.1107/S1600536810042091
_version_ 1782194596866949120
author Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title compound, C(35)H(28)Br(2)N(2)O(2), the piperidone ring adopts a chair conformation and the five-membered ring of the pyrrolidine ring adopts an envelope conformation. The naphthalene ring system makes dihedral angles of 37.12 (8) and 50.62 (9)° with the terminal bromo-substituted benzene rings. The dihedral angle between the two bromo-substituted benzene rings is 72.54 (10)°. In the crystal, adjacent mol­ecules are connected by a pair of inter­molecular C—H⋯O hydrogen bonds, forming an inversion dimer. An intra­molecular O—H⋯N hydrogen bond is also present.
format Text
id pubmed-3009063
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090632010-12-30 11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(28)Br(2)N(2)O(2), the piperidone ring adopts a chair conformation and the five-membered ring of the pyrrolidine ring adopts an envelope conformation. The naphthalene ring system makes dihedral angles of 37.12 (8) and 50.62 (9)° with the terminal bromo-substituted benzene rings. The dihedral angle between the two bromo-substituted benzene rings is 72.54 (10)°. In the crystal, adjacent mol­ecules are connected by a pair of inter­molecular C—H⋯O hydrogen bonds, forming an inversion dimer. An intra­molecular O—H⋯N hydrogen bond is also present. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009063/ /pubmed/21589100 http://dx.doi.org/10.1107/S1600536810042091 Text en © Kumar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Hemamalini, Madhukar
Fun, Hoong-Kun
11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title 11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_full 11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_fullStr 11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_full_unstemmed 11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_short 11-[(E)-4-Bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_sort 11-[(e)-4-bromo­benzyl­idene]-8-(4-bromo­phen­yl)-14-hy­droxy-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009063/
https://www.ncbi.nlm.nih.gov/pubmed/21589100
http://dx.doi.org/10.1107/S1600536810042091
work_keys_str_mv AT kumarrajusuresh 11e4bromobenzylidene84bromophenyl14hydroxy313diazaheptacyclo13711913029021403701923tetracosa1221517192320pentaen10one
AT osmanhasnah 11e4bromobenzylidene84bromophenyl14hydroxy313diazaheptacyclo13711913029021403701923tetracosa1221517192320pentaen10one
AT alimohamedashraf 11e4bromobenzylidene84bromophenyl14hydroxy313diazaheptacyclo13711913029021403701923tetracosa1221517192320pentaen10one
AT hemamalinimadhukar 11e4bromobenzylidene84bromophenyl14hydroxy313diazaheptacyclo13711913029021403701923tetracosa1221517192320pentaen10one
AT funhoongkun 11e4bromobenzylidene84bromophenyl14hydroxy313diazaheptacyclo13711913029021403701923tetracosa1221517192320pentaen10one

Ejemplares similares