8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’

The title compound, C(33)H(45)NO(10), has an aconitine carbon skeleton with four six-membered rings and two five-membered rings. The five-membered rings adopt envelope configurations and the six-membered N-containing heterocyclic ring displays a chair conformation. Two intra­molecular O—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: Zheng, Ling-Li, Li, Yan, Zi, Tie-Ying, Yuan, Ming-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009068/
https://www.ncbi.nlm.nih.gov/pubmed/21588985
http://dx.doi.org/10.1107/S1600536810039887
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author Zheng, Ling-Li
Li, Yan
Zi, Tie-Ying
Yuan, Ming-Yong
author_facet Zheng, Ling-Li
Li, Yan
Zi, Tie-Ying
Yuan, Ming-Yong
author_sort Zheng, Ling-Li
collection PubMed
description The title compound, C(33)H(45)NO(10), has an aconitine carbon skeleton with four six-membered rings and two five-membered rings. The five-membered rings adopt envelope configurations and the six-membered N-containing heterocyclic ring displays a chair conformation. Two intra­molecular O—H⋯O hydrogen bonds occur.
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spelling pubmed-30090682010-12-30 8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’ Zheng, Ling-Li Li, Yan Zi, Tie-Ying Yuan, Ming-Yong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(33)H(45)NO(10), has an aconitine carbon skeleton with four six-membered rings and two five-membered rings. The five-membered rings adopt envelope configurations and the six-membered N-containing heterocyclic ring displays a chair conformation. Two intra­molecular O—H⋯O hydrogen bonds occur. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009068/ /pubmed/21588985 http://dx.doi.org/10.1107/S1600536810039887 Text en © Zheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zheng, Ling-Li
Li, Yan
Zi, Tie-Ying
Yuan, Ming-Yong
8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
title 8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
title_full 8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
title_fullStr 8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
title_full_unstemmed 8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
title_short 8β-Acet­oxy-14α-benzo­yloxy-N-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
title_sort 8β-acet­oxy-14α-benzo­yloxy-n-methyl-13β,15α-dihy­droxy-1α,6α,16β-trimeth­oxy-4β-(meth­oxy­meth­yl)aconitane: hypaconitine isolated from ‘fuzi’
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009068/
https://www.ncbi.nlm.nih.gov/pubmed/21588985
http://dx.doi.org/10.1107/S1600536810039887
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AT zitieying 8bacetoxy14abenzoyloxynmethyl13b15adihydroxy1a6a16btrimethoxy4bmethoxymethylaconitanehypaconitineisolatedfromfuzi
AT yuanmingyong 8bacetoxy14abenzoyloxynmethyl13b15adihydroxy1a6a16btrimethoxy4bmethoxymethylaconitanehypaconitineisolatedfromfuzi

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