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Morpholinium styphnate

In the title mol­ecular salt (systematic name: morpholinium 3-hy­droxy-2,4,6-trinitro­phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendi...

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Detalles Bibliográficos
Autores principales: Kalaivani, D., Malarvizhi, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009074/
https://www.ncbi.nlm.nih.gov/pubmed/21588914
http://dx.doi.org/10.1107/S1600536810038304
Descripción
Sumario:In the title mol­ecular salt (systematic name: morpholinium 3-hy­droxy-2,4,6-trinitro­phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra­molecular O—H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N—H⋯O and trifurcated N—H⋯(O,O,O) hydrogen bonds.