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Morpholinium styphnate

In the title mol­ecular salt (systematic name: morpholinium 3-hy­droxy-2,4,6-trinitro­phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendi...

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Detalles Bibliográficos
Autores principales: Kalaivani, D., Malarvizhi, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009074/
https://www.ncbi.nlm.nih.gov/pubmed/21588914
http://dx.doi.org/10.1107/S1600536810038304
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author Kalaivani, D.
Malarvizhi, R.
author_facet Kalaivani, D.
Malarvizhi, R.
author_sort Kalaivani, D.
collection PubMed
description In the title mol­ecular salt (systematic name: morpholinium 3-hy­droxy-2,4,6-trinitro­phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra­molecular O—H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N—H⋯O and trifurcated N—H⋯(O,O,O) hydrogen bonds.
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spelling pubmed-30090742010-12-30 Morpholinium styphnate Kalaivani, D. Malarvizhi, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt (systematic name: morpholinium 3-hy­droxy-2,4,6-trinitro­phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra­molecular O—H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N—H⋯O and trifurcated N—H⋯(O,O,O) hydrogen bonds. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009074/ /pubmed/21588914 http://dx.doi.org/10.1107/S1600536810038304 Text en © Kalaivani and Malarvizhi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kalaivani, D.
Malarvizhi, R.
Morpholinium styphnate
title Morpholinium styphnate
title_full Morpholinium styphnate
title_fullStr Morpholinium styphnate
title_full_unstemmed Morpholinium styphnate
title_short Morpholinium styphnate
title_sort morpholinium styphnate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009074/
https://www.ncbi.nlm.nih.gov/pubmed/21588914
http://dx.doi.org/10.1107/S1600536810038304
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