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Morpholinium styphnate
In the title molecular salt (systematic name: morpholinium 3-hydroxy-2,4,6-trinitrophenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendi...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009074/ https://www.ncbi.nlm.nih.gov/pubmed/21588914 http://dx.doi.org/10.1107/S1600536810038304 |
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author | Kalaivani, D. Malarvizhi, R. |
author_facet | Kalaivani, D. Malarvizhi, R. |
author_sort | Kalaivani, D. |
collection | PubMed |
description | In the title molecular salt (systematic name: morpholinium 3-hydroxy-2,4,6-trinitrophenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intramolecular O—H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N—H⋯O and trifurcated N—H⋯(O,O,O) hydrogen bonds. |
format | Text |
id | pubmed-3009074 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090742010-12-30 Morpholinium styphnate Kalaivani, D. Malarvizhi, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt (systematic name: morpholinium 3-hydroxy-2,4,6-trinitrophenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (−), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intramolecular O—H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N—H⋯O and trifurcated N—H⋯(O,O,O) hydrogen bonds. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009074/ /pubmed/21588914 http://dx.doi.org/10.1107/S1600536810038304 Text en © Kalaivani and Malarvizhi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kalaivani, D. Malarvizhi, R. Morpholinium styphnate |
title | Morpholinium styphnate |
title_full | Morpholinium styphnate |
title_fullStr | Morpholinium styphnate |
title_full_unstemmed | Morpholinium styphnate |
title_short | Morpholinium styphnate |
title_sort | morpholinium styphnate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009074/ https://www.ncbi.nlm.nih.gov/pubmed/21588914 http://dx.doi.org/10.1107/S1600536810038304 |
work_keys_str_mv | AT kalaivanid morpholiniumstyphnate AT malarvizhir morpholiniumstyphnate |