Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)

The title compound, [Cu(CH(3)CN)(C(12)H(12)N(2))(2)](BF(4))(2), crystallizes with two copper-containing cations and four tetra­fluoro­borate anions in the asymmetric unit. The structure represents a second crystal form of the salt, the first being an acetonitrile solvate [Watton (2009 ▶). Acta Cryst...

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Detalles Bibliográficos
Autor principal: Watton, Stephen P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009076/
https://www.ncbi.nlm.nih.gov/pubmed/21588869
http://dx.doi.org/10.1107/S1600536810042285
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author Watton, Stephen P.
author_facet Watton, Stephen P.
author_sort Watton, Stephen P.
collection PubMed
description The title compound, [Cu(CH(3)CN)(C(12)H(12)N(2))(2)](BF(4))(2), crystallizes with two copper-containing cations and four tetra­fluoro­borate anions in the asymmetric unit. The structure represents a second crystal form of the salt, the first being an acetonitrile solvate [Watton (2009 ▶). Acta Cryst. E65, m585–m586]. The complex cation has a distorted trigonal-bipyramidal geometry, whereas the previous structure exhibits a distorted square-pyramidal geometry. One of the four BF(4) (−) counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17).
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spelling pubmed-30090762010-12-30 Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate) Watton, Stephen P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(CH(3)CN)(C(12)H(12)N(2))(2)](BF(4))(2), crystallizes with two copper-containing cations and four tetra­fluoro­borate anions in the asymmetric unit. The structure represents a second crystal form of the salt, the first being an acetonitrile solvate [Watton (2009 ▶). Acta Cryst. E65, m585–m586]. The complex cation has a distorted trigonal-bipyramidal geometry, whereas the previous structure exhibits a distorted square-pyramidal geometry. One of the four BF(4) (−) counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17). International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009076/ /pubmed/21588869 http://dx.doi.org/10.1107/S1600536810042285 Text en © Stephen P. Watton 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Watton, Stephen P.
Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)
title Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)
title_full Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)
title_fullStr Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)
title_full_unstemmed Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)
title_short Acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(II) bis­(tetra­fluorido­borate)
title_sort acetonitrile­bis­(2,9-dimethyl-1,10-phen­an­throline)copper(ii) bis­(tetra­fluorido­borate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009076/
https://www.ncbi.nlm.nih.gov/pubmed/21588869
http://dx.doi.org/10.1107/S1600536810042285
work_keys_str_mv AT wattonstephenp acetonitrilebis29dimethyl110phenanthrolinecopperiibistetrafluoridoborate

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