Cargando…

4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide

In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methyl­ene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal struct...

Descripción completa

Detalles Bibliográficos
Autores principales: Basanagouda, Mahantesha, Nayak, Susanta K., Guru Row, T. N., Kulkarni, Manohar V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009080/
https://www.ncbi.nlm.nih.gov/pubmed/21588978
http://dx.doi.org/10.1107/S1600536810039693
Descripción
Sumario:In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methyl­ene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal structure is stabilized by weak C—H⋯O inter­actions, leading to the formation of dimers with R (2) (2)(12) graph-set motifs. These dimers are further linked by weak S—O⋯π and π–π contacts [centroid–centroid distance = 3.765 (2) Å], leading to the formation of a layered structure.