Cargando…

4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide

In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methyl­ene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal struct...

Descripción completa

Detalles Bibliográficos
Autores principales: Basanagouda, Mahantesha, Nayak, Susanta K., Guru Row, T. N., Kulkarni, Manohar V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009080/
https://www.ncbi.nlm.nih.gov/pubmed/21588978
http://dx.doi.org/10.1107/S1600536810039693
_version_ 1782194601009872896
author Basanagouda, Mahantesha
Nayak, Susanta K.
Guru Row, T. N.
Kulkarni, Manohar V.
author_facet Basanagouda, Mahantesha
Nayak, Susanta K.
Guru Row, T. N.
Kulkarni, Manohar V.
author_sort Basanagouda, Mahantesha
collection PubMed
description In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methyl­ene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal structure is stabilized by weak C—H⋯O inter­actions, leading to the formation of dimers with R (2) (2)(12) graph-set motifs. These dimers are further linked by weak S—O⋯π and π–π contacts [centroid–centroid distance = 3.765 (2) Å], leading to the formation of a layered structure.
format Text
id pubmed-3009080
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090802010-12-30 4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide Basanagouda, Mahantesha Nayak, Susanta K. Guru Row, T. N. Kulkarni, Manohar V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methyl­ene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal structure is stabilized by weak C—H⋯O inter­actions, leading to the formation of dimers with R (2) (2)(12) graph-set motifs. These dimers are further linked by weak S—O⋯π and π–π contacts [centroid–centroid distance = 3.765 (2) Å], leading to the formation of a layered structure. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009080/ /pubmed/21588978 http://dx.doi.org/10.1107/S1600536810039693 Text en © Basanagouda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Basanagouda, Mahantesha
Nayak, Susanta K.
Guru Row, T. N.
Kulkarni, Manohar V.
4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
title 4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
title_full 4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
title_fullStr 4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
title_full_unstemmed 4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
title_short 4-Azido­methyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
title_sort 4-azido­methyl-7-methyl-2-oxo-2h-chromene-6-sulfonyl azide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009080/
https://www.ncbi.nlm.nih.gov/pubmed/21588978
http://dx.doi.org/10.1107/S1600536810039693
work_keys_str_mv AT basanagoudamahantesha 4azidomethyl7methyl2oxo2hchromene6sulfonylazide
AT nayaksusantak 4azidomethyl7methyl2oxo2hchromene6sulfonylazide
AT gururowtn 4azidomethyl7methyl2oxo2hchromene6sulfonylazide
AT kulkarnimanoharv 4azidomethyl7methyl2oxo2hchromene6sulfonylazide