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4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide
In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methylene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal struct...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009080/ https://www.ncbi.nlm.nih.gov/pubmed/21588978 http://dx.doi.org/10.1107/S1600536810039693 |
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author | Basanagouda, Mahantesha Nayak, Susanta K. Guru Row, T. N. Kulkarni, Manohar V. |
author_facet | Basanagouda, Mahantesha Nayak, Susanta K. Guru Row, T. N. Kulkarni, Manohar V. |
author_sort | Basanagouda, Mahantesha |
collection | PubMed |
description | In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methylene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal structure is stabilized by weak C—H⋯O interactions, leading to the formation of dimers with R (2) (2)(12) graph-set motifs. These dimers are further linked by weak S—O⋯π and π–π contacts [centroid–centroid distance = 3.765 (2) Å], leading to the formation of a layered structure. |
format | Text |
id | pubmed-3009080 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090802010-12-30 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide Basanagouda, Mahantesha Nayak, Susanta K. Guru Row, T. N. Kulkarni, Manohar V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(8)N(6)O(4)S, the plane of the coumarin aromatic ring is twisted by 17.2 (2)° with respect to the plane of the azide group bound to the methylene substituent, whereas it is twisted by 83.2 (2)° to the plane of the azide attached to the sulfonyl group. The crystal structure is stabilized by weak C—H⋯O interactions, leading to the formation of dimers with R (2) (2)(12) graph-set motifs. These dimers are further linked by weak S—O⋯π and π–π contacts [centroid–centroid distance = 3.765 (2) Å], leading to the formation of a layered structure. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009080/ /pubmed/21588978 http://dx.doi.org/10.1107/S1600536810039693 Text en © Basanagouda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Basanagouda, Mahantesha Nayak, Susanta K. Guru Row, T. N. Kulkarni, Manohar V. 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide |
title | 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide |
title_full | 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide |
title_fullStr | 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide |
title_full_unstemmed | 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide |
title_short | 4-Azidomethyl-7-methyl-2-oxo-2H-chromene-6-sulfonyl azide |
title_sort | 4-azidomethyl-7-methyl-2-oxo-2h-chromene-6-sulfonyl azide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009080/ https://www.ncbi.nlm.nih.gov/pubmed/21588978 http://dx.doi.org/10.1107/S1600536810039693 |
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