trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)

The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter­actions are obser...

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Detalles Bibliográficos
Autores principales: Muller, Alfred, Meijboom, Reinout
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009084/
https://www.ncbi.nlm.nih.gov/pubmed/21588880
http://dx.doi.org/10.1107/S1600536810042595
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author Muller, Alfred
Meijboom, Reinout
author_facet Muller, Alfred
Meijboom, Reinout
author_sort Muller, Alfred
collection PubMed
description The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter­actions are observed between the aromatic rings of adjacent mol­ecules, with an inter­planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C—H⋯Cl hydrogen bonds also occur.
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spelling pubmed-30090842010-12-30 trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II) Muller, Alfred Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter­actions are observed between the aromatic rings of adjacent mol­ecules, with an inter­planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C—H⋯Cl hydrogen bonds also occur. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009084/ /pubmed/21588880 http://dx.doi.org/10.1107/S1600536810042595 Text en © Muller and Meijboom 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muller, Alfred
Meijboom, Reinout
trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)
title trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)
title_full trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)
title_fullStr trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)
title_full_unstemmed trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)
title_short trans-Dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(II)
title_sort trans-dichloridobis{[4-(dimethyl­amino)­phen­yl]diphenyl­phosphane}palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009084/
https://www.ncbi.nlm.nih.gov/pubmed/21588880
http://dx.doi.org/10.1107/S1600536810042595
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