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(E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide
In the title molecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridinering and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009086/ https://www.ncbi.nlm.nih.gov/pubmed/21589027 http://dx.doi.org/10.1107/S1600536810040936 |
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author | Sankar, C. Pandiarajan, K. Thiruvalluvar, A. Gayathri, P. |
author_facet | Sankar, C. Pandiarajan, K. Thiruvalluvar, A. Gayathri, P. |
author_sort | Sankar, C. |
collection | PubMed |
description | In the title molecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridinering and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring makes dihedral angles of 64.13 (8) and 10.75 (8)° with the phenyl rings at the 2 and 6 positions, respectively. The dihedral angle between the two phenyl rings is 53.57 (8)°. The phenyl rings and one of the methyl groups at position 3 have an equatorial orientation. In the crystal, molecules are linked by N—H⋯O and C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-3009086 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090862010-12-30 (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide Sankar, C. Pandiarajan, K. Thiruvalluvar, A. Gayathri, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridinering and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring makes dihedral angles of 64.13 (8) and 10.75 (8)° with the phenyl rings at the 2 and 6 positions, respectively. The dihedral angle between the two phenyl rings is 53.57 (8)°. The phenyl rings and one of the methyl groups at position 3 have an equatorial orientation. In the crystal, molecules are linked by N—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009086/ /pubmed/21589027 http://dx.doi.org/10.1107/S1600536810040936 Text en © Sankar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sankar, C. Pandiarajan, K. Thiruvalluvar, A. Gayathri, P. (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
title | (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
title_full | (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
title_fullStr | (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
title_full_unstemmed | (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
title_short | (E)-N′-(3,3-Dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
title_sort | (e)-n′-(3,3-dimethyl-2,6-diphenylpiperidin-4-ylidene)isonicotinohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009086/ https://www.ncbi.nlm.nih.gov/pubmed/21589027 http://dx.doi.org/10.1107/S1600536810040936 |
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