Cargando…

(E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide

In the title mol­ecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridine­ring and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring...

Descripción completa

Detalles Bibliográficos
Autores principales: Sankar, C., Pandiarajan, K., Thiruvalluvar, A., Gayathri, P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009086/
https://www.ncbi.nlm.nih.gov/pubmed/21589027
http://dx.doi.org/10.1107/S1600536810040936
_version_ 1782194602418110464
author Sankar, C.
Pandiarajan, K.
Thiruvalluvar, A.
Gayathri, P.
author_facet Sankar, C.
Pandiarajan, K.
Thiruvalluvar, A.
Gayathri, P.
author_sort Sankar, C.
collection PubMed
description In the title mol­ecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridine­ring and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring makes dihedral angles of 64.13 (8) and 10.75 (8)° with the phenyl rings at the 2 and 6 positions, respectively. The dihedral angle between the two phenyl rings is 53.57 (8)°. The phenyl rings and one of the methyl groups at position 3 have an equatorial orientation. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds.
format Text
id pubmed-3009086
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090862010-12-30 (E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide Sankar, C. Pandiarajan, K. Thiruvalluvar, A. Gayathri, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridine­ring and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring makes dihedral angles of 64.13 (8) and 10.75 (8)° with the phenyl rings at the 2 and 6 positions, respectively. The dihedral angle between the two phenyl rings is 53.57 (8)°. The phenyl rings and one of the methyl groups at position 3 have an equatorial orientation. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009086/ /pubmed/21589027 http://dx.doi.org/10.1107/S1600536810040936 Text en © Sankar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sankar, C.
Pandiarajan, K.
Thiruvalluvar, A.
Gayathri, P.
(E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
title (E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
title_full (E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
title_fullStr (E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
title_full_unstemmed (E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
title_short (E)-N′-(3,3-Dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
title_sort (e)-n′-(3,3-dimethyl-2,6-diphenyl­piperidin-4-yl­idene)isonicotinohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009086/
https://www.ncbi.nlm.nih.gov/pubmed/21589027
http://dx.doi.org/10.1107/S1600536810040936
work_keys_str_mv AT sankarc en33dimethyl26diphenylpiperidin4ylideneisonicotinohydrazide
AT pandiarajank en33dimethyl26diphenylpiperidin4ylideneisonicotinohydrazide
AT thiruvalluvara en33dimethyl26diphenylpiperidin4ylideneisonicotinohydrazide
AT gayathrip en33dimethyl26diphenylpiperidin4ylideneisonicotinohydrazide