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Acridinium 2-hydroxybenzoate
In the title compound, C(13)H(10)N(+)·C(7)H(5)O(3) (−) or (acrH)(+)(Hsal)(−), the asymmetric unit contains one acridinium cation and one salicylate anion. The acridinium N atom is protonated and the carboxylic acid group of salicylic acid is deprotonated. Both moieties are planar, with an r.m.s. d...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009090/ https://www.ncbi.nlm.nih.gov/pubmed/21589158 http://dx.doi.org/10.1107/S160053681004345X |
| Sumario: | In the title compound, C(13)H(10)N(+)·C(7)H(5)O(3) (−) or (acrH)(+)(Hsal)(−), the asymmetric unit contains one acridinium cation and one salicylate anion. The acridinium N atom is protonated and the carboxylic acid group of salicylic acid is deprotonated. Both moieties are planar, with an r.m.s. deviation of 0.0127 Å for the acr cation and 0.0235 ° for the sal anion. They are aligned with a dihedral angle of 71.68 (3)° between them. The crystal structure is stabilized by a network of intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. C—H⋯π interactions are also present. |
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