Acridinium 2-hy­droxy­benzoate

In the title compound, C(13)H(10)N(+)·C(7)H(5)O(3) (−) or (acrH)(+)(Hsal)(−), the asymmetric unit contains one acridinium cation and one salicylate anion. The acridinium N atom is protonated and the carb­oxy­lic acid group of salicylic acid is deprotonated. Both moieties are planar, with an r.m.s. d...

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Autores principales: Eshtiagh-Hosseini, Hossein, Hassanpoor, Azam, Mirzaei, Masoud, Salimi, Ali R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009090/
https://www.ncbi.nlm.nih.gov/pubmed/21589158
http://dx.doi.org/10.1107/S160053681004345X
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author Eshtiagh-Hosseini, Hossein
Hassanpoor, Azam
Mirzaei, Masoud
Salimi, Ali R.
author_facet Eshtiagh-Hosseini, Hossein
Hassanpoor, Azam
Mirzaei, Masoud
Salimi, Ali R.
author_sort Eshtiagh-Hosseini, Hossein
collection PubMed
description In the title compound, C(13)H(10)N(+)·C(7)H(5)O(3) (−) or (acrH)(+)(Hsal)(−), the asymmetric unit contains one acridinium cation and one salicylate anion. The acridinium N atom is protonated and the carb­oxy­lic acid group of salicylic acid is deprotonated. Both moieties are planar, with an r.m.s. deviation of 0.0127 Å for the acr cation and 0.0235 ° for the sal anion. They are aligned with a dihedral angle of 71.68 (3)° between them. The crystal structure is stabilized by a network of inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. C—H⋯π inter­actions are also present.
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spelling pubmed-30090902010-12-30 Acridinium 2-hy­droxy­benzoate Eshtiagh-Hosseini, Hossein Hassanpoor, Azam Mirzaei, Masoud Salimi, Ali R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)N(+)·C(7)H(5)O(3) (−) or (acrH)(+)(Hsal)(−), the asymmetric unit contains one acridinium cation and one salicylate anion. The acridinium N atom is protonated and the carb­oxy­lic acid group of salicylic acid is deprotonated. Both moieties are planar, with an r.m.s. deviation of 0.0127 Å for the acr cation and 0.0235 ° for the sal anion. They are aligned with a dihedral angle of 71.68 (3)° between them. The crystal structure is stabilized by a network of inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. C—H⋯π inter­actions are also present. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009090/ /pubmed/21589158 http://dx.doi.org/10.1107/S160053681004345X Text en © Eshtiagh-Hosseini et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Eshtiagh-Hosseini, Hossein
Hassanpoor, Azam
Mirzaei, Masoud
Salimi, Ali R.
Acridinium 2-hy­droxy­benzoate
title Acridinium 2-hy­droxy­benzoate
title_full Acridinium 2-hy­droxy­benzoate
title_fullStr Acridinium 2-hy­droxy­benzoate
title_full_unstemmed Acridinium 2-hy­droxy­benzoate
title_short Acridinium 2-hy­droxy­benzoate
title_sort acridinium 2-hy­droxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009090/
https://www.ncbi.nlm.nih.gov/pubmed/21589158
http://dx.doi.org/10.1107/S160053681004345X
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AT hassanpoorazam acridinium2hydroxybenzoate
AT mirzaeimasoud acridinium2hydroxybenzoate
AT salimialir acridinium2hydroxybenzoate

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