Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine

The title compound, C(21)H(24)N(4)S(3), is a tripodal Schiff base that was obtained from the reaction of tris­(2-amino­eth­yl)amine (tren) and thio­phene-3-carbaldehyde. The compound forms a cavity with approximate C3 symmetry. One of the thio­phene units is disordered in a 0.764 (2):0.236 (2) ratio...

Descripción completa

Detalles Bibliográficos
Autores principales: Işıklan, Muhammet, Pramanik, Avijit, Fronczek, Frank R., Hossain, Md. Alamgir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009092/
https://www.ncbi.nlm.nih.gov/pubmed/21588946
http://dx.doi.org/10.1107/S1600536810039206
_version_ 1782194604133580800
author Işıklan, Muhammet
Pramanik, Avijit
Fronczek, Frank R.
Hossain, Md. Alamgir
author_facet Işıklan, Muhammet
Pramanik, Avijit
Fronczek, Frank R.
Hossain, Md. Alamgir
author_sort Işıklan, Muhammet
collection PubMed
description The title compound, C(21)H(24)N(4)S(3), is a tripodal Schiff base that was obtained from the reaction of tris­(2-amino­eth­yl)amine (tren) and thio­phene-3-carbaldehyde. The compound forms a cavity with approximate C3 symmetry. One of the thio­phene units is disordered in a 0.764 (2):0.236 (2) ratio. In the crystal, the three thio­phene ligands are involved in intra­molecular C—H⋯π inter­actions and the mol­ecules are connected by C—H⋯N inter­actions, forming hydrogen-bonded chains.
format Text
id pubmed-3009092
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090922010-12-30 Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine Işıklan, Muhammet Pramanik, Avijit Fronczek, Frank R. Hossain, Md. Alamgir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(24)N(4)S(3), is a tripodal Schiff base that was obtained from the reaction of tris­(2-amino­eth­yl)amine (tren) and thio­phene-3-carbaldehyde. The compound forms a cavity with approximate C3 symmetry. One of the thio­phene units is disordered in a 0.764 (2):0.236 (2) ratio. In the crystal, the three thio­phene ligands are involved in intra­molecular C—H⋯π inter­actions and the mol­ecules are connected by C—H⋯N inter­actions, forming hydrogen-bonded chains. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009092/ /pubmed/21588946 http://dx.doi.org/10.1107/S1600536810039206 Text en © Işıklan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Işıklan, Muhammet
Pramanik, Avijit
Fronczek, Frank R.
Hossain, Md. Alamgir
Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
title Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
title_full Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
title_fullStr Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
title_full_unstemmed Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
title_short Tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
title_sort tris{2-[(3-thien­yl)methyl­idene­amino]­eth­yl}amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009092/
https://www.ncbi.nlm.nih.gov/pubmed/21588946
http://dx.doi.org/10.1107/S1600536810039206
work_keys_str_mv AT isıklanmuhammet tris23thienylmethylideneaminoethylamine
AT pramanikavijit tris23thienylmethylideneaminoethylamine
AT fronczekfrankr tris23thienylmethylideneaminoethylamine
AT hossainmdalamgir tris23thienylmethylideneaminoethylamine

Ejemplares similares