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catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]

The Pb(II )atom in the title compound, {[Pb(2)(C(7)H(6)NO(2))(4)]}(n), is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitro­gen donor and one oxygen donor in the axial positions. Two mol­...

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Detalles Bibliográficos
Autores principales: Shen, Fwu Ming, Lush, Shie Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009093/
https://www.ncbi.nlm.nih.gov/pubmed/21588853
http://dx.doi.org/10.1107/S1600536810041322
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author Shen, Fwu Ming
Lush, Shie Fu
author_facet Shen, Fwu Ming
Lush, Shie Fu
author_sort Shen, Fwu Ming
collection PubMed
description The Pb(II )atom in the title compound, {[Pb(2)(C(7)H(6)NO(2))(4)]}(n), is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitro­gen donor and one oxygen donor in the axial positions. Two mol­ecules are linked through a centre of inversion, forming a dinuclear entity. These entities are linked in a μ(3)-bridging mode through the amino N atom and two carboxyl­ate O atoms into a chain along the b axis. Classical inter­molecular N—H⋯O hydrogen bonding is observed in the structure. The supra­molecular structure is consolidated by π–π stacking inter­actions with centroid–centroid distances between benzene rings of 3.837 (8) Å.
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spelling pubmed-30090932010-12-30 catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)] Shen, Fwu Ming Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pb(II )atom in the title compound, {[Pb(2)(C(7)H(6)NO(2))(4)]}(n), is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitro­gen donor and one oxygen donor in the axial positions. Two mol­ecules are linked through a centre of inversion, forming a dinuclear entity. These entities are linked in a μ(3)-bridging mode through the amino N atom and two carboxyl­ate O atoms into a chain along the b axis. Classical inter­molecular N—H⋯O hydrogen bonding is observed in the structure. The supra­molecular structure is consolidated by π–π stacking inter­actions with centroid–centroid distances between benzene rings of 3.837 (8) Å. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009093/ /pubmed/21588853 http://dx.doi.org/10.1107/S1600536810041322 Text en © Shen and Lush 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Fwu Ming
Lush, Shie Fu
catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
title catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
title_full catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
title_fullStr catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
title_full_unstemmed catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
title_short catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
title_sort catena-poly[bis(μ(3)-3-aminobenzoato-κ(4) n:o:o,o′)bis(μ(2)-3-aminobenzoato-κ(3) o,o′:o)dilead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009093/
https://www.ncbi.nlm.nih.gov/pubmed/21588853
http://dx.doi.org/10.1107/S1600536810041322
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