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catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)]
The Pb(II )atom in the title compound, {[Pb(2)(C(7)H(6)NO(2))(4)]}(n), is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitrogen donor and one oxygen donor in the axial positions. Two mol...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009093/ https://www.ncbi.nlm.nih.gov/pubmed/21588853 http://dx.doi.org/10.1107/S1600536810041322 |
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author | Shen, Fwu Ming Lush, Shie Fu |
author_facet | Shen, Fwu Ming Lush, Shie Fu |
author_sort | Shen, Fwu Ming |
collection | PubMed |
description | The Pb(II )atom in the title compound, {[Pb(2)(C(7)H(6)NO(2))(4)]}(n), is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitrogen donor and one oxygen donor in the axial positions. Two molecules are linked through a centre of inversion, forming a dinuclear entity. These entities are linked in a μ(3)-bridging mode through the amino N atom and two carboxylate O atoms into a chain along the b axis. Classical intermolecular N—H⋯O hydrogen bonding is observed in the structure. The supramolecular structure is consolidated by π–π stacking interactions with centroid–centroid distances between benzene rings of 3.837 (8) Å. |
format | Text |
id | pubmed-3009093 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090932010-12-30 catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)] Shen, Fwu Ming Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pb(II )atom in the title compound, {[Pb(2)(C(7)H(6)NO(2))(4)]}(n), is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitrogen donor and one oxygen donor in the axial positions. Two molecules are linked through a centre of inversion, forming a dinuclear entity. These entities are linked in a μ(3)-bridging mode through the amino N atom and two carboxylate O atoms into a chain along the b axis. Classical intermolecular N—H⋯O hydrogen bonding is observed in the structure. The supramolecular structure is consolidated by π–π stacking interactions with centroid–centroid distances between benzene rings of 3.837 (8) Å. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009093/ /pubmed/21588853 http://dx.doi.org/10.1107/S1600536810041322 Text en © Shen and Lush 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shen, Fwu Ming Lush, Shie Fu catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4) N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3) O,O′:O)dilead(II)] |
title |
catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4)
N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3)
O,O′:O)dilead(II)] |
title_full |
catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4)
N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3)
O,O′:O)dilead(II)] |
title_fullStr |
catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4)
N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3)
O,O′:O)dilead(II)] |
title_full_unstemmed |
catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4)
N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3)
O,O′:O)dilead(II)] |
title_short |
catena-Poly[bis(μ(3)-3-aminobenzoato-κ(4)
N:O:O,O′)bis(μ(2)-3-aminobenzoato-κ(3)
O,O′:O)dilead(II)] |
title_sort | catena-poly[bis(μ(3)-3-aminobenzoato-κ(4)
n:o:o,o′)bis(μ(2)-3-aminobenzoato-κ(3)
o,o′:o)dilead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009093/ https://www.ncbi.nlm.nih.gov/pubmed/21588853 http://dx.doi.org/10.1107/S1600536810041322 |
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