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[2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)

In the title compound, [Cu(C(13)H(20)N(3)O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino­bis­(propyl­amine) and salicyl­aldehyde. The three N and the O atoms occupy equatorial positions, while t...

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Detalles Bibliográficos
Autores principales: Assey, Gervas E., Butcher, Anand M., Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009097/
https://www.ncbi.nlm.nih.gov/pubmed/21588891
http://dx.doi.org/10.1107/S1600536810042923
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author Assey, Gervas E.
Butcher, Anand M.
Butcher, Ray J.
Gultneh, Yilma
author_facet Assey, Gervas E.
Butcher, Anand M.
Butcher, Ray J.
Gultneh, Yilma
author_sort Assey, Gervas E.
collection PubMed
description In the title compound, [Cu(C(13)H(20)N(3)O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino­bis­(propyl­amine) and salicyl­aldehyde. The three N and the O atoms occupy equatorial positions, while the Br atom occupies an axial position. The amine H atoms form inter­molecular hydrogen bonds with the Br and O atoms of adjoining mol­ecules
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spelling pubmed-30090972010-12-30 [2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II) Assey, Gervas E. Butcher, Anand M. Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(20)N(3)O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino­bis­(propyl­amine) and salicyl­aldehyde. The three N and the O atoms occupy equatorial positions, while the Br atom occupies an axial position. The amine H atoms form inter­molecular hydrogen bonds with the Br and O atoms of adjoining mol­ecules International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009097/ /pubmed/21588891 http://dx.doi.org/10.1107/S1600536810042923 Text en © Assey et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Assey, Gervas E.
Butcher, Anand M.
Butcher, Ray J.
Gultneh, Yilma
[2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)
title [2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)
title_full [2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)
title_fullStr [2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)
title_full_unstemmed [2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)
title_short [2-({3-[(3-Amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) O,N,N′′,N′′′]bromidocopper(II)
title_sort [2-({3-[(3-amino­prop­yl)amino]­prop­yl}imino­meth­yl)phenolato-κ(4) o,n,n′′,n′′′]bromidocopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009097/
https://www.ncbi.nlm.nih.gov/pubmed/21588891
http://dx.doi.org/10.1107/S1600536810042923
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