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4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)

In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion i...

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Detalles Bibliográficos
Autores principales: Nenwa, Justin, Belombe, Michel M., Ngoune, Jean, Fokwa, Boniface P. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009100/
https://www.ncbi.nlm.nih.gov/pubmed/21588840
http://dx.doi.org/10.1107/S1600536810040353
Descripción
Sumario:In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion is six-coordinated in a distorted (4 + 2) octa­hedral geometry with four equatorial O atoms of two nearly coplanar oxalate and two quasi-axial aqua O atoms. In the crystal, the protonated N atoms of the pyridine rings are hydrogen bonded to the carbonyl O atoms of the anions, forming chains along [010]. These chains are connected by lateral O—H⋯O hydrogen bonds, stabilizing the structure.