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4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion i...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009100/ https://www.ncbi.nlm.nih.gov/pubmed/21588840 http://dx.doi.org/10.1107/S1600536810040353 |
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author | Nenwa, Justin Belombe, Michel M. Ngoune, Jean Fokwa, Boniface P. T. |
author_facet | Nenwa, Justin Belombe, Michel M. Ngoune, Jean Fokwa, Boniface P. T. |
author_sort | Nenwa, Justin |
collection | PubMed |
description | In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion is six-coordinated in a distorted (4 + 2) octahedral geometry with four equatorial O atoms of two nearly coplanar oxalate and two quasi-axial aqua O atoms. In the crystal, the protonated N atoms of the pyridine rings are hydrogen bonded to the carbonyl O atoms of the anions, forming chains along [010]. These chains are connected by lateral O—H⋯O hydrogen bonds, stabilizing the structure. |
format | Text |
id | pubmed-3009100 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30091002010-12-30 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) Nenwa, Justin Belombe, Michel M. Ngoune, Jean Fokwa, Boniface P. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion is six-coordinated in a distorted (4 + 2) octahedral geometry with four equatorial O atoms of two nearly coplanar oxalate and two quasi-axial aqua O atoms. In the crystal, the protonated N atoms of the pyridine rings are hydrogen bonded to the carbonyl O atoms of the anions, forming chains along [010]. These chains are connected by lateral O—H⋯O hydrogen bonds, stabilizing the structure. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009100/ /pubmed/21588840 http://dx.doi.org/10.1107/S1600536810040353 Text en © Nenwa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Nenwa, Justin Belombe, Michel M. Ngoune, Jean Fokwa, Boniface P. T. 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) |
title | 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2)
O
(1),O
(2)]chromate(III) |
title_full | 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2)
O
(1),O
(2)]chromate(III) |
title_fullStr | 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2)
O
(1),O
(2)]chromate(III) |
title_full_unstemmed | 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2)
O
(1),O
(2)]chromate(III) |
title_short | 4-(Dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2)
O
(1),O
(2)]chromate(III) |
title_sort | 4-(dimethylamino)pyridinium trans-diaquabis[oxalato(2−)-κ(2)
o
(1),o
(2)]chromate(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009100/ https://www.ncbi.nlm.nih.gov/pubmed/21588840 http://dx.doi.org/10.1107/S1600536810040353 |
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