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4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)

In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion i...

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Autores principales: Nenwa, Justin, Belombe, Michel M., Ngoune, Jean, Fokwa, Boniface P. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009100/
https://www.ncbi.nlm.nih.gov/pubmed/21588840
http://dx.doi.org/10.1107/S1600536810040353
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author Nenwa, Justin
Belombe, Michel M.
Ngoune, Jean
Fokwa, Boniface P. T.
author_facet Nenwa, Justin
Belombe, Michel M.
Ngoune, Jean
Fokwa, Boniface P. T.
author_sort Nenwa, Justin
collection PubMed
description In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion is six-coordinated in a distorted (4 + 2) octa­hedral geometry with four equatorial O atoms of two nearly coplanar oxalate and two quasi-axial aqua O atoms. In the crystal, the protonated N atoms of the pyridine rings are hydrogen bonded to the carbonyl O atoms of the anions, forming chains along [010]. These chains are connected by lateral O—H⋯O hydrogen bonds, stabilizing the structure.
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spelling pubmed-30091002010-12-30 4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) Nenwa, Justin Belombe, Michel M. Ngoune, Jean Fokwa, Boniface P. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(7)H(11)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], the asymmetric unit contains one half-cation and one half-anion. The Cr atom, the C and N atoms involved in C— N(exocyclic) bonding and the N and H atoms of N—H groups lie on twofold rotation axis. The Cr(III) atom of the complex anion is six-coordinated in a distorted (4 + 2) octa­hedral geometry with four equatorial O atoms of two nearly coplanar oxalate and two quasi-axial aqua O atoms. In the crystal, the protonated N atoms of the pyridine rings are hydrogen bonded to the carbonyl O atoms of the anions, forming chains along [010]. These chains are connected by lateral O—H⋯O hydrogen bonds, stabilizing the structure. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009100/ /pubmed/21588840 http://dx.doi.org/10.1107/S1600536810040353 Text en © Nenwa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nenwa, Justin
Belombe, Michel M.
Ngoune, Jean
Fokwa, Boniface P. T.
4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
title 4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
title_full 4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
title_fullStr 4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
title_full_unstemmed 4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
title_short 4-(Dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III)
title_sort 4-(dimethyl­amino)­pyridinium trans-diaqua­bis­[oxalato(2−)-κ(2) o (1),o (2)]chromate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009100/
https://www.ncbi.nlm.nih.gov/pubmed/21588840
http://dx.doi.org/10.1107/S1600536810040353
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