10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate

In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (−), adjacent cations and anions are connected through C—H⋯O, C—H⋯F and S–O⋯π inter­actions, while neighboring cations via π–π inter­actions [centroid–centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are orie...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009101/
https://www.ncbi.nlm.nih.gov/pubmed/21588973
http://dx.doi.org/10.1107/S160053681003953X
Descripción
Sumario:In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (−), adjacent cations and anions are connected through C—H⋯O, C—H⋯F and S–O⋯π inter­actions, while neighboring cations via π–π inter­actions [centroid–centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°. The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure.

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