10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate

In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (−), adjacent cations and anions are connected through C—H⋯O, C—H⋯F and S–O⋯π inter­actions, while neighboring cations via π–π inter­actions [centroid–centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are orie...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009101/
https://www.ncbi.nlm.nih.gov/pubmed/21588973
http://dx.doi.org/10.1107/S160053681003953X
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author Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (−), adjacent cations and anions are connected through C—H⋯O, C—H⋯F and S–O⋯π inter­actions, while neighboring cations via π–π inter­actions [centroid–centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°. The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure.
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spelling pubmed-30091012010-12-30 10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (−), adjacent cations and anions are connected through C—H⋯O, C—H⋯F and S–O⋯π inter­actions, while neighboring cations via π–π inter­actions [centroid–centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°. The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009101/ /pubmed/21588973 http://dx.doi.org/10.1107/S160053681003953X Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
title 10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
title_full 10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
title_fullStr 10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
title_short 10-Methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
title_sort 10-methyl-9-[2-(propan-2-yl)phenoxy­carbonyl]­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009101/
https://www.ncbi.nlm.nih.gov/pubmed/21588973
http://dx.doi.org/10.1107/S160053681003953X
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AT krzyminskikarol 10methyl92propan2ylphenoxycarbonylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 10methyl92propan2ylphenoxycarbonylacridiniumtrifluoromethanesulfonate

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