N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine

In the title compound, C(27)H(25)NP(2), the diphenyl­phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74 (5) and 68.23 (4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an a...

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Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009108/
https://www.ncbi.nlm.nih.gov/pubmed/21589062
http://dx.doi.org/10.1107/S1600536810041711
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author Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_facet Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_sort Engelbrecht, Ilana
collection PubMed
description In the title compound, C(27)H(25)NP(2), the diphenyl­phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74 (5) and 68.23 (4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098 (2) Å.
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spelling pubmed-30091082010-12-30 N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(25)NP(2), the diphenyl­phosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74 (5) and 68.23 (4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098 (2) Å. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009108/ /pubmed/21589062 http://dx.doi.org/10.1107/S1600536810041711 Text en © Engelbrecht et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine
title N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine
title_full N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine
title_fullStr N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine
title_full_unstemmed N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine
title_short N,N-Bis(diphenyl­phosphanyl)cyclo­propyl­amine
title_sort n,n-bis(diphenyl­phosphanyl)cyclo­propyl­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009108/
https://www.ncbi.nlm.nih.gov/pubmed/21589062
http://dx.doi.org/10.1107/S1600536810041711
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AT visserhendrikg nnbisdiphenylphosphanylcyclopropylamine
AT roodtandreas nnbisdiphenylphosphanylcyclopropylamine

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