(Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)

The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron–porphyrin complex with an axial eth­oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth­oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.078 (2) Å and...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Xu, Nan, Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009112/
https://www.ncbi.nlm.nih.gov/pubmed/21588876
http://dx.doi.org/10.1107/S1600536810041024
Descripción
Sumario:The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron–porphyrin complex with an axial eth­oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth­oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.078 (2) Å and the Fe—O distance is 1.8232 (18) Å. The eth­oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe—O—C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.

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