(Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)

The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron–porphyrin complex with an axial eth­oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth­oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.078 (2) Å and...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Xu, Nan, Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009112/
https://www.ncbi.nlm.nih.gov/pubmed/21588876
http://dx.doi.org/10.1107/S1600536810041024
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author Cheng, Lin
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
author_facet Cheng, Lin
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
author_sort Cheng, Lin
collection PubMed
description The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron–porphyrin complex with an axial eth­oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth­oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.078 (2) Å and the Fe—O distance is 1.8232 (18) Å. The eth­oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe—O—C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.
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spelling pubmed-30091122010-12-30 (Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III) Cheng, Lin Xu, Nan Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron–porphyrin complex with an axial eth­oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth­oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.078 (2) Å and the Fe—O distance is 1.8232 (18) Å. The eth­oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe—O—C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009112/ /pubmed/21588876 http://dx.doi.org/10.1107/S1600536810041024 Text en © Cheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
(Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)
title (Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)
title_full (Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)
title_fullStr (Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)
title_full_unstemmed (Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)
title_short (Ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(III)
title_sort (ethanolato)[2,3,7,8,12,13,17,18-octa­ethylporphyrinato(2−)]iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009112/
https://www.ncbi.nlm.nih.gov/pubmed/21588876
http://dx.doi.org/10.1107/S1600536810041024
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AT powelldouglasr ethanolato237812131718octaethylporphyrinato2ironiii
AT richteraddogeorgeb ethanolato237812131718octaethylporphyrinato2ironiii

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