2-Cyano­quinolin-1-ium hydrogen sulfate

The title salt, C(10)H(7)N(2) (+)·HSO(4) (−), is formed by the transfer of a proton from H(2)SO(4) to the N atom of 2-cyano­quinoline during crystallization. The quinoline ring system is approximately planar with a maximum deviation of 0.013 (3) Å. In the crystal, the cations are linked to the anion...

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Detalles Bibliográficos
Autores principales: Loh, Wan-Sin, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009120/
https://www.ncbi.nlm.nih.gov/pubmed/21588923
http://dx.doi.org/10.1107/S160053681003878X
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author Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Loh, Wan-Sin
collection PubMed
description The title salt, C(10)H(7)N(2) (+)·HSO(4) (−), is formed by the transfer of a proton from H(2)SO(4) to the N atom of 2-cyano­quinoline during crystallization. The quinoline ring system is approximately planar with a maximum deviation of 0.013 (3) Å. In the crystal, the cations are linked to the anions via inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming a layered network.
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spelling pubmed-30091202010-12-30 2-Cyano­quinolin-1-ium hydrogen sulfate Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(10)H(7)N(2) (+)·HSO(4) (−), is formed by the transfer of a proton from H(2)SO(4) to the N atom of 2-cyano­quinoline during crystallization. The quinoline ring system is approximately planar with a maximum deviation of 0.013 (3) Å. In the crystal, the cations are linked to the anions via inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming a layered network. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009120/ /pubmed/21588923 http://dx.doi.org/10.1107/S160053681003878X Text en © Loh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Cyano­quinolin-1-ium hydrogen sulfate
title 2-Cyano­quinolin-1-ium hydrogen sulfate
title_full 2-Cyano­quinolin-1-ium hydrogen sulfate
title_fullStr 2-Cyano­quinolin-1-ium hydrogen sulfate
title_full_unstemmed 2-Cyano­quinolin-1-ium hydrogen sulfate
title_short 2-Cyano­quinolin-1-ium hydrogen sulfate
title_sort 2-cyano­quinolin-1-ium hydrogen sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009120/
https://www.ncbi.nlm.nih.gov/pubmed/21588923
http://dx.doi.org/10.1107/S160053681003878X
work_keys_str_mv AT lohwansin 2cyanoquinolin1iumhydrogensulfate
AT hemamalinimadhukar 2cyanoquinolin1iumhydrogensulfate
AT funhoongkun 2cyanoquinolin1iumhydrogensulfate

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