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Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]

The molecule of the title compound, [Ni(4)(CH(3)O)(4)(C(8)H(7)O(3))(4)(CH(3)OH)(4)], has S (4) symmetry. Each of the four Ni(II) atoms occupies every other corner of a cube, with the alternate corners occupied by μ(3)-methano­late bridging groups linking to three Ni(II) atoms. Each Ni(II) atom is in...

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Autores principales: Ayikoe, Kouassi, Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009121/
https://www.ncbi.nlm.nih.gov/pubmed/21588902
http://dx.doi.org/10.1107/S1600536810043497
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author Ayikoe, Kouassi
Butcher, Ray J.
Gultneh, Yilma
author_facet Ayikoe, Kouassi
Butcher, Ray J.
Gultneh, Yilma
author_sort Ayikoe, Kouassi
collection PubMed
description The molecule of the title compound, [Ni(4)(CH(3)O)(4)(C(8)H(7)O(3))(4)(CH(3)OH)(4)], has S (4) symmetry. Each of the four Ni(II) atoms occupies every other corner of a cube, with the alternate corners occupied by μ(3)-methano­late bridging groups linking to three Ni(II) atoms. Each Ni(II) atom is in an O(6) octa­hedral coordination environment formed by three O atoms from three μ(3)-methano­late groups, one from methanol, and two others from a bidentate 2-formyl-6-meth­oxy­phenolate ligand. The Ni—O bond distances range from 2.0020 (14) to 2.0938 (14) Å, the cis bond angles range from 81.74 (6) to 97.63°, and the trans bond angles range from 168.76 (5) to 175.22 (6)°. There are bifurcated hydrogen-bonding inter­actions between the coordinated methanol OH groups and both the phenolic and meth­oxy O atoms of an adjoining 2-formyl-6-meth­oxy­phenolate moiety. In addition, there are weak inter­molecular C—H⋯O inter­actions involving the meth­oxy O atoms.
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spelling pubmed-30091212010-12-30 Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)] Ayikoe, Kouassi Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Ni(4)(CH(3)O)(4)(C(8)H(7)O(3))(4)(CH(3)OH)(4)], has S (4) symmetry. Each of the four Ni(II) atoms occupies every other corner of a cube, with the alternate corners occupied by μ(3)-methano­late bridging groups linking to three Ni(II) atoms. Each Ni(II) atom is in an O(6) octa­hedral coordination environment formed by three O atoms from three μ(3)-methano­late groups, one from methanol, and two others from a bidentate 2-formyl-6-meth­oxy­phenolate ligand. The Ni—O bond distances range from 2.0020 (14) to 2.0938 (14) Å, the cis bond angles range from 81.74 (6) to 97.63°, and the trans bond angles range from 168.76 (5) to 175.22 (6)°. There are bifurcated hydrogen-bonding inter­actions between the coordinated methanol OH groups and both the phenolic and meth­oxy O atoms of an adjoining 2-formyl-6-meth­oxy­phenolate moiety. In addition, there are weak inter­molecular C—H⋯O inter­actions involving the meth­oxy O atoms. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009121/ /pubmed/21588902 http://dx.doi.org/10.1107/S1600536810043497 Text en © Ayikoe et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ayikoe, Kouassi
Butcher, Ray J.
Gultneh, Yilma
Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]
title Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]
title_full Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]
title_fullStr Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]
title_full_unstemmed Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]
title_short Tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(II)]
title_sort tetra-μ(3)-methano­lato-tetra­kis­[(2-formyl-6-meth­oxy­phenolato)methano­lnickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009121/
https://www.ncbi.nlm.nih.gov/pubmed/21588902
http://dx.doi.org/10.1107/S1600536810043497
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