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Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)]
The molecule of the title compound, [Ni(4)(CH(3)O)(4)(C(8)H(7)O(3))(4)(CH(3)OH)(4)], has S (4) symmetry. Each of the four Ni(II) atoms occupies every other corner of a cube, with the alternate corners occupied by μ(3)-methanolate bridging groups linking to three Ni(II) atoms. Each Ni(II) atom is in...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009121/ https://www.ncbi.nlm.nih.gov/pubmed/21588902 http://dx.doi.org/10.1107/S1600536810043497 |
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author | Ayikoe, Kouassi Butcher, Ray J. Gultneh, Yilma |
author_facet | Ayikoe, Kouassi Butcher, Ray J. Gultneh, Yilma |
author_sort | Ayikoe, Kouassi |
collection | PubMed |
description | The molecule of the title compound, [Ni(4)(CH(3)O)(4)(C(8)H(7)O(3))(4)(CH(3)OH)(4)], has S (4) symmetry. Each of the four Ni(II) atoms occupies every other corner of a cube, with the alternate corners occupied by μ(3)-methanolate bridging groups linking to three Ni(II) atoms. Each Ni(II) atom is in an O(6) octahedral coordination environment formed by three O atoms from three μ(3)-methanolate groups, one from methanol, and two others from a bidentate 2-formyl-6-methoxyphenolate ligand. The Ni—O bond distances range from 2.0020 (14) to 2.0938 (14) Å, the cis bond angles range from 81.74 (6) to 97.63°, and the trans bond angles range from 168.76 (5) to 175.22 (6)°. There are bifurcated hydrogen-bonding interactions between the coordinated methanol OH groups and both the phenolic and methoxy O atoms of an adjoining 2-formyl-6-methoxyphenolate moiety. In addition, there are weak intermolecular C—H⋯O interactions involving the methoxy O atoms. |
format | Text |
id | pubmed-3009121 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30091212010-12-30 Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] Ayikoe, Kouassi Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Ni(4)(CH(3)O)(4)(C(8)H(7)O(3))(4)(CH(3)OH)(4)], has S (4) symmetry. Each of the four Ni(II) atoms occupies every other corner of a cube, with the alternate corners occupied by μ(3)-methanolate bridging groups linking to three Ni(II) atoms. Each Ni(II) atom is in an O(6) octahedral coordination environment formed by three O atoms from three μ(3)-methanolate groups, one from methanol, and two others from a bidentate 2-formyl-6-methoxyphenolate ligand. The Ni—O bond distances range from 2.0020 (14) to 2.0938 (14) Å, the cis bond angles range from 81.74 (6) to 97.63°, and the trans bond angles range from 168.76 (5) to 175.22 (6)°. There are bifurcated hydrogen-bonding interactions between the coordinated methanol OH groups and both the phenolic and methoxy O atoms of an adjoining 2-formyl-6-methoxyphenolate moiety. In addition, there are weak intermolecular C—H⋯O interactions involving the methoxy O atoms. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009121/ /pubmed/21588902 http://dx.doi.org/10.1107/S1600536810043497 Text en © Ayikoe et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ayikoe, Kouassi Butcher, Ray J. Gultneh, Yilma Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] |
title | Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] |
title_full | Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] |
title_fullStr | Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] |
title_full_unstemmed | Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] |
title_short | Tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(II)] |
title_sort | tetra-μ(3)-methanolato-tetrakis[(2-formyl-6-methoxyphenolato)methanolnickel(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009121/ https://www.ncbi.nlm.nih.gov/pubmed/21588902 http://dx.doi.org/10.1107/S1600536810043497 |
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