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catena-Poly[silver(I)-μ-acridine-9-carboxyl­ato-κ(3) N:O,O′]

In the title coordination polymer, [Ag(C(14)H(8)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from two symmetry-related acridine-9-carboxyl­ate ligands in a distorted trigonal-planar geometry. The metal atoms are connected by the ligands to form chains running parallel to...

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Detalles Bibliográficos
Autores principales: Yang, Ya-Qing, Chen, Xiao-Ye, Huo, Shu-Min, Ma, Yan-Ru, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009123/
https://www.ncbi.nlm.nih.gov/pubmed/21588897
http://dx.doi.org/10.1107/S1600536810043199
Descripción
Sumario:In the title coordination polymer, [Ag(C(14)H(8)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from two symmetry-related acridine-9-carboxyl­ate ligands in a distorted trigonal-planar geometry. The metal atoms are connected by the ligands to form chains running parallel to the b axis. π–π stacking inter­actions [centroid-to-centroid distances 3.757 (2)–3.820 (2) Å] and weak Ag⋯O inter­actions further link the chains to form a layer network parallel to the ab plane. The Ag(I) cation is disordered over two positions, with refined site-occupancy factors of 0.73 (3):0.27 (3).