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catena-Poly[silver(I)-μ-acridine-9-carboxylato-κ(3) N:O,O′]
In the title coordination polymer, [Ag(C(14)H(8)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from two symmetry-related acridine-9-carboxylate ligands in a distorted trigonal-planar geometry. The metal atoms are connected by the ligands to form chains running parallel to...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009123/ https://www.ncbi.nlm.nih.gov/pubmed/21588897 http://dx.doi.org/10.1107/S1600536810043199 |
Sumario: | In the title coordination polymer, [Ag(C(14)H(8)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from two symmetry-related acridine-9-carboxylate ligands in a distorted trigonal-planar geometry. The metal atoms are connected by the ligands to form chains running parallel to the b axis. π–π stacking interactions [centroid-to-centroid distances 3.757 (2)–3.820 (2) Å] and weak Ag⋯O interactions further link the chains to form a layer network parallel to the ab plane. The Ag(I) cation is disordered over two positions, with refined site-occupancy factors of 0.73 (3):0.27 (3). |
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