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3-(2,5-Dimethylfuran-3-yl)-1H-pyrazol-5-ol–ethyl 3-(propan-2-ylidene)carbazate (1/1)
In the title 1:1 adduct, C(6)H(12)N(2)O(2)·C(9)H(10)N(2)O(2), the maximum deviations from the 1H-pyrazole-5-ol and furan rings are 0.014 (1) and 0.003 (1) Å, respectively. The dihedral angle formed between the 1H-pyrazol-5-ol and 2,5-dimethylfuran rings is 21.07 (5)°. In the crystal, pairs of inter...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009126/ https://www.ncbi.nlm.nih.gov/pubmed/21589178 http://dx.doi.org/10.1107/S1600536810043886 |
Sumario: | In the title 1:1 adduct, C(6)H(12)N(2)O(2)·C(9)H(10)N(2)O(2), the maximum deviations from the 1H-pyrazole-5-ol and furan rings are 0.014 (1) and 0.003 (1) Å, respectively. The dihedral angle formed between the 1H-pyrazol-5-ol and 2,5-dimethylfuran rings is 21.07 (5)°. In the crystal, pairs of intermolecular O—H⋯N hydrogen bonds form inversion dimers of the 3-(2,5-dimethylfuran-3-yl)-1H-pyrazol-5-ol species, generating R (2) (2)(8) ring motifs. Molecules are further linked by intermolecular N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds to form ribbons along the [010] direction containing bifurcated R (1) (2)(5) and R (2) (1)(7) ring motifs. Further stablization of the packing is provided by weak π–π [centroid–centroid distance = 3.5686 (15) Å] and C—H⋯π interactions. |
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