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Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate

The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hy­droxy­phenyl­acetate (hpaa) anions, two 4,4′-bipyridine mol­ecules (bipy) and two water mol­ecules; an additional water mol­ecule of solvation is also present in the crystal structure. Each...

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Detalles Bibliográficos
Autores principales: Liu, Jia-Lu, Liu, Jian-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009128/
https://www.ncbi.nlm.nih.gov/pubmed/21588892
http://dx.doi.org/10.1107/S1600536810043023
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author Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang
author_facet Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang
author_sort Liu, Jia-Lu
collection PubMed
description The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hy­droxy­phenyl­acetate (hpaa) anions, two 4,4′-bipyridine mol­ecules (bipy) and two water mol­ecules; an additional water mol­ecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water mol­ecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the Nd(III) ions in the bridging and bridging tridentate modes. Extensive O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonding stabilizes the crystal structure.
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spelling pubmed-30091282010-12-30 Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hy­droxy­phenyl­acetate (hpaa) anions, two 4,4′-bipyridine mol­ecules (bipy) and two water mol­ecules; an additional water mol­ecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water mol­ecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the Nd(III) ions in the bridging and bridging tridentate modes. Extensive O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonding stabilizes the crystal structure. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009128/ /pubmed/21588892 http://dx.doi.org/10.1107/S1600536810043023 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang
Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate
title Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate
title_full Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate
title_fullStr Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate
title_full_unstemmed Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate
title_short Tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­(4,4′-bi­pyridine-κN)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) O,O]neodymium(III)} monohydrate
title_sort tetra­kis[μ-2-(4-hy­droxy­phenyl)­acetato]-κ(3) o,o′:o;κ(3) o:o,o′-bis­{aqua­(4,4′-bi­pyridine-κn)bis­[2-(4-hy­droxy­phenyl)­acetato-κ(2) o,o]neodymium(iii)} monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009128/
https://www.ncbi.nlm.nih.gov/pubmed/21588892
http://dx.doi.org/10.1107/S1600536810043023
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