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Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O]neodymium(III)} monohydrate
The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hydroxyphenylacetate (hpaa) anions, two 4,4′-bipyridine molecules (bipy) and two water molecules; an additional water molecule of solvation is also present in the crystal structure. Each...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009128/ https://www.ncbi.nlm.nih.gov/pubmed/21588892 http://dx.doi.org/10.1107/S1600536810043023 |
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author | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
author_facet | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
author_sort | Liu, Jia-Lu |
collection | PubMed |
description | The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hydroxyphenylacetate (hpaa) anions, two 4,4′-bipyridine molecules (bipy) and two water molecules; an additional water molecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water molecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the Nd(III) ions in the bridging and bridging tridentate modes. Extensive O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonding stabilizes the crystal structure. |
format | Text |
id | pubmed-3009128 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30091282010-12-30 Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O]neodymium(III)} monohydrate Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hydroxyphenylacetate (hpaa) anions, two 4,4′-bipyridine molecules (bipy) and two water molecules; an additional water molecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water molecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the Nd(III) ions in the bridging and bridging tridentate modes. Extensive O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonding stabilizes the crystal structure. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009128/ /pubmed/21588892 http://dx.doi.org/10.1107/S1600536810043023 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O]neodymium(III)} monohydrate |
title | Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O]neodymium(III)} monohydrate |
title_full | Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O]neodymium(III)} monohydrate |
title_fullStr | Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O]neodymium(III)} monohydrate |
title_full_unstemmed | Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O]neodymium(III)} monohydrate |
title_short | Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O]neodymium(III)} monohydrate |
title_sort | tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
o,o′:o;κ(3)
o:o,o′-bis{aqua(4,4′-bipyridine-κn)bis[2-(4-hydroxyphenyl)acetato-κ(2)
o,o]neodymium(iii)} monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009128/ https://www.ncbi.nlm.nih.gov/pubmed/21588892 http://dx.doi.org/10.1107/S1600536810043023 |
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