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Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octahedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the othe...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009130/ https://www.ncbi.nlm.nih.gov/pubmed/21588893 http://dx.doi.org/10.1107/S1600536810042558 |
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author | Wan, Chong-Qing Xiao, Nai-You Wang, Zi-Jia |
author_facet | Wan, Chong-Qing Xiao, Nai-You Wang, Zi-Jia |
author_sort | Wan, Chong-Qing |
collection | PubMed |
description | In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octahedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further interconnected through weak C—H⋯O and C—H⋯S hydrogen-bonding interactions. |
format | Text |
id | pubmed-3009130 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30091302010-12-30 Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] Wan, Chong-Qing Xiao, Nai-You Wang, Zi-Jia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octahedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further interconnected through weak C—H⋯O and C—H⋯S hydrogen-bonding interactions. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009130/ /pubmed/21588893 http://dx.doi.org/10.1107/S1600536810042558 Text en © Wan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wan, Chong-Qing Xiao, Nai-You Wang, Zi-Jia Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] |
title | Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] |
title_full | Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] |
title_fullStr | Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] |
title_full_unstemmed | Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] |
title_short | Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)] |
title_sort | poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009130/ https://www.ncbi.nlm.nih.gov/pubmed/21588893 http://dx.doi.org/10.1107/S1600536810042558 |
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