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{μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III)
In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetradentate Schiff base ligand. The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Sc...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009133/ https://www.ncbi.nlm.nih.gov/pubmed/21588850 http://dx.doi.org/10.1107/S1600536810040833 |
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author | Xing, Jing-Chun Cui, Xiao-Guang Zhang, Bing Li, Wen-Zhi |
author_facet | Xing, Jing-Chun Cui, Xiao-Guang Zhang, Bing Li, Wen-Zhi |
author_sort | Xing, Jing-Chun |
collection | PubMed |
description | In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetradentate Schiff base ligand. The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand. The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17). |
format | Text |
id | pubmed-3009133 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30091332010-12-30 {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) Xing, Jing-Chun Cui, Xiao-Guang Zhang, Bing Li, Wen-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetradentate Schiff base ligand. The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand. The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17). International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009133/ /pubmed/21588850 http://dx.doi.org/10.1107/S1600536810040833 Text en © Xing et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xing, Jing-Chun Cui, Xiao-Guang Zhang, Bing Li, Wen-Zhi {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) |
title | {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) |
title_full | {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) |
title_fullStr | {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) |
title_full_unstemmed | {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) |
title_short | {μ(2)-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)neodymium(III) |
title_sort | {μ(2)-6,6′-dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(ii)neodymium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009133/ https://www.ncbi.nlm.nih.gov/pubmed/21588850 http://dx.doi.org/10.1107/S1600536810040833 |
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