Cargando…

Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate

In the title complex, [Cu(C(13)H(11)N(3)O(2))(2)(C(12)H(8)N(2))](NO(3))(2), the Cu(II )atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the Cu(II)atom by a pyridine N atom. These four atoms...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Xiu-Qing, Li, Chun-Ying, Bian, He-Dong, Yu, Qing, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009134/
https://www.ncbi.nlm.nih.gov/pubmed/21588803
http://dx.doi.org/10.1107/S1600536810038985
_version_ 1782194614902456320
author Zhang, Xiu-Qing
Li, Chun-Ying
Bian, He-Dong
Yu, Qing
Liang, Hong
author_facet Zhang, Xiu-Qing
Li, Chun-Ying
Bian, He-Dong
Yu, Qing
Liang, Hong
author_sort Zhang, Xiu-Qing
collection PubMed
description In the title complex, [Cu(C(13)H(11)N(3)O(2))(2)(C(12)H(8)N(2))](NO(3))(2), the Cu(II )atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the Cu(II)atom by a pyridine N atom. These four atoms form a slightly distorted square-planar N(4) donor set. In the packing, two additional Cu⋯O inter­actions occur [Cu⋯O = 2.462 (2) Å], resulting in a typical Jahn–Teller-distorted octahedral environment around the Cu atom. N—H⋯O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68 (2):0.32 (2) ratio.
format Text
id pubmed-3009134
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30091342010-12-30 Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate Zhang, Xiu-Qing Li, Chun-Ying Bian, He-Dong Yu, Qing Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(13)H(11)N(3)O(2))(2)(C(12)H(8)N(2))](NO(3))(2), the Cu(II )atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the Cu(II)atom by a pyridine N atom. These four atoms form a slightly distorted square-planar N(4) donor set. In the packing, two additional Cu⋯O inter­actions occur [Cu⋯O = 2.462 (2) Å], resulting in a typical Jahn–Teller-distorted octahedral environment around the Cu atom. N—H⋯O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68 (2):0.32 (2) ratio. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009134/ /pubmed/21588803 http://dx.doi.org/10.1107/S1600536810038985 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiu-Qing
Li, Chun-Ying
Bian, He-Dong
Yu, Qing
Liang, Hong
Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
title Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
title_full Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
title_fullStr Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
title_full_unstemmed Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
title_short Bis(N′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate
title_sort bis(n′-benzoyl­pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009134/
https://www.ncbi.nlm.nih.gov/pubmed/21588803
http://dx.doi.org/10.1107/S1600536810038985
work_keys_str_mv AT zhangxiuqing bisnbenzoylpyridine4carbohydrazide110phenanthrolinecopperiidinitrate
AT lichunying bisnbenzoylpyridine4carbohydrazide110phenanthrolinecopperiidinitrate
AT bianhedong bisnbenzoylpyridine4carbohydrazide110phenanthrolinecopperiidinitrate
AT yuqing bisnbenzoylpyridine4carbohydrazide110phenanthrolinecopperiidinitrate
AT lianghong bisnbenzoylpyridine4carbohydrazide110phenanthrolinecopperiidinitrate