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(2-Carboxyacetato-κ(2) O (1),O (1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN(4)O(2) octahedron. The formula units are connected by N—H⋯O hydrogen bonds...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009135/ https://www.ncbi.nlm.nih.gov/pubmed/21588885 http://dx.doi.org/10.1107/S1600536810042637 |
| _version_ | 1782194615140483072 |
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| author | Ou, Guang-Chuan Ng, Seik Weng |
| author_facet | Ou, Guang-Chuan Ng, Seik Weng |
| author_sort | Ou, Guang-Chuan |
| collection | PubMed |
| description | In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN(4)O(2) octahedron. The formula units are connected by N—H⋯O hydrogen bonds into centrosymmetric dimers. Further N—H⋯O and O—H⋯O hydrogen bonds link the complex molecules and the perchlorate ions. |
| format | Text |
| id | pubmed-3009135 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30091352010-12-30 (2-Carboxyacetato-κ(2) O (1),O (1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate Ou, Guang-Chuan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN(4)O(2) octahedron. The formula units are connected by N—H⋯O hydrogen bonds into centrosymmetric dimers. Further N—H⋯O and O—H⋯O hydrogen bonds link the complex molecules and the perchlorate ions. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009135/ /pubmed/21588885 http://dx.doi.org/10.1107/S1600536810042637 Text en © Ou and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ou, Guang-Chuan Ng, Seik Weng (2-Carboxyacetato-κ(2) O (1),O (1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
| title | (2-Carboxyacetato-κ(2)
O
(1),O
(1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
| title_full | (2-Carboxyacetato-κ(2)
O
(1),O
(1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
| title_fullStr | (2-Carboxyacetato-κ(2)
O
(1),O
(1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
| title_full_unstemmed | (2-Carboxyacetato-κ(2)
O
(1),O
(1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
| title_short | (2-Carboxyacetato-κ(2)
O
(1),O
(1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
| title_sort | (2-carboxyacetato-κ(2)
o
(1),o
(1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
n,n′,n′′,n′′′)nickel(ii) perchlorate acetonitrile solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009135/ https://www.ncbi.nlm.nih.gov/pubmed/21588885 http://dx.doi.org/10.1107/S1600536810042637 |
| work_keys_str_mv | AT ouguangchuan 2carboxyacetatok2o1o1rac557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliiperchlorateacetonitrilesolvate AT ngseikweng 2carboxyacetatok2o1o1rac557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliiperchlorateacetonitrilesolvate |