(2-Carb­oxy­acetato-κ(2) O (1),O (1′))(rac-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate

In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxyl­ate monoanion. The geometry is a distorted NiN(4)O(2) octa­hedron. The formula units are connected by N—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009135/
https://www.ncbi.nlm.nih.gov/pubmed/21588885
http://dx.doi.org/10.1107/S1600536810042637

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009135/
https://www.ncbi.nlm.nih.gov/pubmed/21588885
http://dx.doi.org/10.1107/S1600536810042637

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