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(2-Carboxyacetato-κ(2) O (1),O (1′))(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN(4)O(2) octahedron. The formula units are connected by N—H⋯O hydrogen bonds...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009135/ https://www.ncbi.nlm.nih.gov/pubmed/21588885 http://dx.doi.org/10.1107/S1600536810042637 |