(1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine

The title compound, C(16)H(16)Cl(2)N(2), was synthesized by the condensation reaction between 4,5-dichloro-o-phenyl­ene­diamine and (1R)-(-)-camphorquinone in boiling acetic acid. The two crystallographically independent mol­ecules in the unit cell are related by a pseudo-inversion center.

Detalles Bibliográficos
Autores principales: Crundwell, Guy, Glagovich, Neil
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009136/
https://www.ncbi.nlm.nih.gov/pubmed/21589196
http://dx.doi.org/10.1107/S1600536810044016
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author Crundwell, Guy
Glagovich, Neil
author_facet Crundwell, Guy
Glagovich, Neil
author_sort Crundwell, Guy
collection PubMed
description The title compound, C(16)H(16)Cl(2)N(2), was synthesized by the condensation reaction between 4,5-dichloro-o-phenyl­ene­diamine and (1R)-(-)-camphorquinone in boiling acetic acid. The two crystallographically independent mol­ecules in the unit cell are related by a pseudo-inversion center.
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spelling pubmed-30091362010-12-30 (1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine Crundwell, Guy Glagovich, Neil Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)Cl(2)N(2), was synthesized by the condensation reaction between 4,5-dichloro-o-phenyl­ene­diamine and (1R)-(-)-camphorquinone in boiling acetic acid. The two crystallographically independent mol­ecules in the unit cell are related by a pseudo-inversion center. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009136/ /pubmed/21589196 http://dx.doi.org/10.1107/S1600536810044016 Text en © Crundwell and Glagovich 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Crundwell, Guy
Glagovich, Neil
(1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
title (1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
title_full (1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
title_fullStr (1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
title_full_unstemmed (1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
title_short (1R,4S)-7,8-Dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
title_sort (1r,4s)-7,8-dichloro-1,2,3,4-tetra­hydro-1,11,11-trimethyl-1,4-methano­phenazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009136/
https://www.ncbi.nlm.nih.gov/pubmed/21589196
http://dx.doi.org/10.1107/S1600536810044016
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