Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)

In the title compound, [Ni(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on an inversion center and adopts a distorted trans-NiO(2)N(4) octa­hedral geometry, coordinated by two N,O-bidentate 4,4,5,5-tetra­methyl-2-(5-methyl­imidazol-4-yl)-2-imidazoline-1-oxyl 3-oxide nitronyl nitroxide rad...

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Detalles Bibliográficos
Autores principales: Chang, Jiu Li, Gao, Zhi Yong, Zhao, Ning
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009139/
https://www.ncbi.nlm.nih.gov/pubmed/21588896
http://dx.doi.org/10.1107/S1600536810042455
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author Chang, Jiu Li
Gao, Zhi Yong
Zhao, Ning
author_facet Chang, Jiu Li
Gao, Zhi Yong
Zhao, Ning
author_sort Chang, Jiu Li
collection PubMed
description In the title compound, [Ni(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on an inversion center and adopts a distorted trans-NiO(2)N(4) octa­hedral geometry, coordinated by two N,O-bidentate 4,4,5,5-tetra­methyl-2-(5-methyl­imidazol-4-yl)-2-imidazoline-1-oxyl 3-oxide nitronyl nitroxide radical ligands and two monodentate azide anions.
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spelling pubmed-30091392010-12-30 Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II) Chang, Jiu Li Gao, Zhi Yong Zhao, Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on an inversion center and adopts a distorted trans-NiO(2)N(4) octa­hedral geometry, coordinated by two N,O-bidentate 4,4,5,5-tetra­methyl-2-(5-methyl­imidazol-4-yl)-2-imidazoline-1-oxyl 3-oxide nitronyl nitroxide radical ligands and two monodentate azide anions. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009139/ /pubmed/21588896 http://dx.doi.org/10.1107/S1600536810042455 Text en © Chang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chang, Jiu Li
Gao, Zhi Yong
Zhao, Ning
Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)
title Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)
title_full Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)
title_fullStr Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)
title_full_unstemmed Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)
title_short Diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) N (1),O (3)]nickel(II)
title_sort diazido­bis­[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl 3-oxide-κ(2) n (1),o (3)]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009139/
https://www.ncbi.nlm.nih.gov/pubmed/21588896
http://dx.doi.org/10.1107/S1600536810042455
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AT gaozhiyong diazidobis4455tetramethyl213thiazol2yl2imidazoline1oxyl3oxidek2n1o3nickelii
AT zhaoning diazidobis4455tetramethyl213thiazol2yl2imidazoline1oxyl3oxidek2n1o3nickelii

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