1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)

In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra­hedral geometry. Each [MnCl(4)](2−) anion is connected to the 1-cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane dications by N—H⋯Cl hydrogen bon...

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Detalles Bibliográficos
Autores principales: Guo, Min, Zhao, Min Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009148/
https://www.ncbi.nlm.nih.gov/pubmed/21588843
http://dx.doi.org/10.1107/S160053681004047X
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author Guo, Min
Zhao, Min Min
author_facet Guo, Min
Zhao, Min Min
author_sort Guo, Min
collection PubMed
description In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra­hedral geometry. Each [MnCl(4)](2−) anion is connected to the 1-cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane dications by N—H⋯Cl hydrogen bonds, forming chains parallel to [001].
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spelling pubmed-30091482010-12-30 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II) Guo, Min Zhao, Min Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra­hedral geometry. Each [MnCl(4)](2−) anion is connected to the 1-cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane dications by N—H⋯Cl hydrogen bonds, forming chains parallel to [001]. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009148/ /pubmed/21588843 http://dx.doi.org/10.1107/S160053681004047X Text en © Guo and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Min
Zhao, Min Min
1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)
title 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)
title_full 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)
title_fullStr 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)
title_full_unstemmed 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)
title_short 1-Cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(II)
title_sort 1-cyano­methyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridomanganate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009148/
https://www.ncbi.nlm.nih.gov/pubmed/21588843
http://dx.doi.org/10.1107/S160053681004047X
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