{6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)

In the title complex, [Cu(C(26)H(26)N(2)O(4))], the Cu(II) ion lies on a crystallographic twofold rotation axis and is coordinated in a slightly distorted square-planar environment. The dihedral angle between the central benzene ring and each of the two symmetry-related outer benzene rings is 5.1 (2...

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Detalles Bibliográficos
Autores principales: Jamshidvand, Arezoo, Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009165/
https://www.ncbi.nlm.nih.gov/pubmed/21588889
http://dx.doi.org/10.1107/S1600536810042789
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author Jamshidvand, Arezoo
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Jamshidvand, Arezoo
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Jamshidvand, Arezoo
collection PubMed
description In the title complex, [Cu(C(26)H(26)N(2)O(4))], the Cu(II) ion lies on a crystallographic twofold rotation axis and is coordinated in a slightly distorted square-planar environment. The dihedral angle between the central benzene ring and each of the two symmetry-related outer benzene rings is 5.1 (2)°. The crystal structure is stabilized by inter­molecular π–π inter­actions with centroid–centroid distances in the range 3.466 (2)–3.6431 (16) Å.
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spelling pubmed-30091652010-12-30 {6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II) Jamshidvand, Arezoo Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(26)H(26)N(2)O(4))], the Cu(II) ion lies on a crystallographic twofold rotation axis and is coordinated in a slightly distorted square-planar environment. The dihedral angle between the central benzene ring and each of the two symmetry-related outer benzene rings is 5.1 (2)°. The crystal structure is stabilized by inter­molecular π–π inter­actions with centroid–centroid distances in the range 3.466 (2)–3.6431 (16) Å. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009165/ /pubmed/21588889 http://dx.doi.org/10.1107/S1600536810042789 Text en © Jamshidvand et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jamshidvand, Arezoo
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
{6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title {6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_full {6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_fullStr {6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_full_unstemmed {6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_short {6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_sort {6,6′-dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009165/
https://www.ncbi.nlm.nih.gov/pubmed/21588889
http://dx.doi.org/10.1107/S1600536810042789
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AT kiareza 66diethoxy2245dimethylophenylenebisnitrilomethylidynediphenolatocopperii
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